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Nano Research 2022, 15(10): 8983-8990 https://doi.org/10.1007/s12274-022-4545-6
Research Article | Issue | Published: 11 July 2022

Enhanced ionic diffusion interface in hierarchical metal-organic framework@layered double hydroxide for high-performance hybrid supercapacitors

Show Author's Information Yanan Zhang1,  Junlei Chen1,  Chenyang Su1,  Keyao Chen1,  Huabin Zhang2,  Yuhao Yang1,  Wenhuan Huang1( )
Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
KAUST Catalysis Center, King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia
Keywords:
electrodeposition, interface, supercapacitor, metal-organic framework (MOF), layered double hydroxides (LDHs)
Topics:
Supercapacitor
Cite this article:
Zhang Y, Chen J, Su C, et al. Enhanced ionic diffusion interface in hierarchical metal-organic framework@layered double hydroxide for high-performance hybrid supercapacitors. Nano Research, 2022, 15(10): 8983-8990. https://doi.org/10.1007/s12274-022-4545-6
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Abstract Full text Electronic supplementary material About this article

Layered double hydroxides (LDHs) with abundant accessible active sites are promising electrode materials for hybrid supercapacitor (HSC) due to their ultrahigh theoretical capacitances. However, the structural agglomeration of LDH leads to poor rate capability and durability. Herein, we construct a diffusion-controlled interface in hierarchical architecture of metal-organic framework (MOF) HKUST-1@cobalt-nickel LDH (denoted as HKUST-1@CoNiLDH) through an in situ etching/electro-deposition strategy. The rapid charge transfer and ionic diffusion in HKUST-1@CoNiLDH deliver a remarkable specific capacity of 297.23 mAh·g−1 at 1 A·g−1, superior to mostly reported LDH-based electrodes. More importantly, the as-prepared HKUST-1@CoNiLDH//activated carbon HSC exhibit a high energy density of 39.8 Wh·kg−1 at a power density of 799.9 W·kg−1 with an outstanding capacitance retention of 90% after 5,000 charge–discharge cycles. The in-depth understanding of the ionic diffusion among the MOF/LDH interfaces will greatly promote the further development of designing and synthesizing high performance energy conversion and storage devices.


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Electronic supplementary material
About this article

Enhanced ionic diffusion interface in hierarchical metal-organic framework@layered double hydroxide for high-performance hybrid supercapacitors

Show Author's information Yanan Zhang1, Junlei Chen1, Chenyang Su1, Keyao Chen1, Huabin Zhang2, Yuhao Yang1, Wenhuan Huang1( )
Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
KAUST Catalysis Center, King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia

Abstract

Layered double hydroxides (LDHs) with abundant accessible active sites are promising electrode materials for hybrid supercapacitor (HSC) due to their ultrahigh theoretical capacitances. However, the structural agglomeration of LDH leads to poor rate capability and durability. Herein, we construct a diffusion-controlled interface in hierarchical architecture of metal-organic framework (MOF) HKUST-1@cobalt-nickel LDH (denoted as HKUST-1@CoNiLDH) through an in situ etching/electro-deposition strategy. The rapid charge transfer and ionic diffusion in HKUST-1@CoNiLDH deliver a remarkable specific capacity of 297.23 mAh·g−1 at 1 A·g−1, superior to mostly reported LDH-based electrodes. More importantly, the as-prepared HKUST-1@CoNiLDH//activated carbon HSC exhibit a high energy density of 39.8 Wh·kg−1 at a power density of 799.9 W·kg−1 with an outstanding capacitance retention of 90% after 5,000 charge–discharge cycles. The in-depth understanding of the ionic diffusion among the MOF/LDH interfaces will greatly promote the further development of designing and synthesizing high performance energy conversion and storage devices.

Keywords: electrodeposition, interface, supercapacitor, metal-organic framework (MOF), layered double hydroxides (LDHs)

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Publication history
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Acknowledgements

Publication history

Received: 28 February 2022
Revised: 16 May 2022
Accepted: 16 May 2022
Published: 11 July 2022
Issue date: October 2022

Copyright

© Tsinghua University Press 2022

Acknowledgements

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 22001156), the Youth Talent Fund of University Association for Science and Technology in Shaanxi, China (No. 20210602), and Science Foundation of Science and Technology Department of Shaanxi Province (No. 2021JQ-533).

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