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Nano Research 2022, 15(4): 3514-3532 https://doi.org/10.1007/s12274-021-3980-0
Review Article | Issue | Published: 17 December 2021

Combining metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs): Emerging opportunities for new materials and applications

Show Author's Information Zhixi Li1,§,  Jun Guo2,§( ),  Yue Wan1,  Yutian Qin1,  Meiting Zhao1( )
Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China
School of Chemistry, Tiangong University, Tianjin 300387, China

§ Zhixi Li and Jun Guo contributed equally to this work.

Keywords:
hybrids, applications, metal-organic frameworks (MOFs), coordination chemistry, covalent organic frameworks (COFs), covalent chemistry
Topics:
Organic frameworks
Cite this article:
Li Z, Guo J, Wan Y, et al. Combining metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs): Emerging opportunities for new materials and applications. Nano Research, 2022, 15(4): 3514-3532. https://doi.org/10.1007/s12274-021-3980-0
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Abstract Full text About this article

In the past decades, metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) basically enjoy the coordination chemistry and covalent chemistry, respectively, and such uniqueness has become the major obstacle hampering their further scope diversity and application multi-functionalization. Inspired from the principle of organic retrosynthesis, combining coordination bond and covalent bond together offers additional opportunities for constructing novel MOFs, COFs and MOF@COF hybrids as well as confer on them superior performances in versatile application fields. In this review, we firstly classify and summarize the recently reported synthesis strategies based on the integration of metal–ligand coordination and dynamic covalent bonds. Then, the application performances of as-constructed MOFs, COFs as well as MOF@COF hybrids are discussed and highlighted in the fields of adsorption, separation, catalysis, biosensing, energy storage and so on. Last, our personal insights of the remaining challenges and further prospects are also provided, in order to trigger much more inspirations and endeavors for this hot research field.


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About this article

Combining metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs): Emerging opportunities for new materials and applications

Show Author's information Zhixi Li1,§, Jun Guo2,§( ), Yue Wan1, Yutian Qin1, Meiting Zhao1( )
Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China
School of Chemistry, Tiangong University, Tianjin 300387, China

§ Zhixi Li and Jun Guo contributed equally to this work.

Abstract

In the past decades, metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) basically enjoy the coordination chemistry and covalent chemistry, respectively, and such uniqueness has become the major obstacle hampering their further scope diversity and application multi-functionalization. Inspired from the principle of organic retrosynthesis, combining coordination bond and covalent bond together offers additional opportunities for constructing novel MOFs, COFs and MOF@COF hybrids as well as confer on them superior performances in versatile application fields. In this review, we firstly classify and summarize the recently reported synthesis strategies based on the integration of metal–ligand coordination and dynamic covalent bonds. Then, the application performances of as-constructed MOFs, COFs as well as MOF@COF hybrids are discussed and highlighted in the fields of adsorption, separation, catalysis, biosensing, energy storage and so on. Last, our personal insights of the remaining challenges and further prospects are also provided, in order to trigger much more inspirations and endeavors for this hot research field.

Keywords: hybrids, applications, metal-organic frameworks (MOFs), coordination chemistry, covalent organic frameworks (COFs), covalent chemistry

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Publication history
Copyright
Acknowledgements

Publication history

Received: 22 August 2021
Revised: 22 September 2021
Accepted: 05 November 2021
Published: 17 December 2021
Issue date: April 2022

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21905195 and 22103055), the Natural Science Foundation of Tianjin City (No. 20JCYBJC00800) and PEIYANG Young Scholars Program of Tianjin University (No. 2020XRX-0023).

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