References(41)
[1]
Sun, T. T.; Xu, L. B.; Wang, D. S.; Li, Y. D. Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion. Nano Res. 2019, 12, 2067-2080.
[2]
Song, R. B.; Zhu, W. L.; Fu, J. J.; Chen, Y.; Liu, L.; Zhang, J. R.; Lin, Y.; Zhu, J. J. Electrode materials engineering in electrocatalytic CO2 reduction: Energy input and conversion efficiency. Adv. Mater., in press, DOI: .
[3]
Wu, J. J.; Sharifi, T.; Gao, Y.; Zhang, T. Y.; Ajayan, P. M. Emerging carbon-based heterogeneous catalysts for electrochemical reduction of carbon dioxide into value-added chemicals. Adv. Mater. 2019, 31, 1804257.
[4]
Zhu, D. D.; Liu, J. L.; Qiao, S. Z. Recent advances in inorganic heterogeneous electrocatalysts for reduction of carbon dioxide. Adv. Mater. 2016, 28, 3423-3452.
[5]
Lin, R.; Ma, X. L.; Cheong, W. C.; Zhang, C.; Zhu, W.; Pei, J. J.; Zhang, K. Y.; Wang, B.; Liang, S. Y.; Liu, Y. X. et al. PdAg bimetallic electrocatalyst for highly selective reduction of CO2 with low COOH* formation energy and facile CO desorption. Nano Res. 2019, 12, 2866-2871.
[6]
Kumar, B.; Asadi, M.; Pisasale, D.; Sinha-Ray, S.; Rosen, B. A.; Haasch, R.; Abiade, J.; Yarin, A. L.; Salehi-Khojin, A. Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction. Nat. Commun. 2013, 4, 2819.
[7]
Liu, X.; Dai, L. M. Carbon-based metal-free catalysts. Nat. Rev. Mater. 2016, 1, 16064.
[8]
Yan, X. C.; Jia, Y.; Yao, X. D. Defects on carbons for electrocatalytic oxygen reduction. Chem. Soc. Rev. 2018, 47, 7628-7658.
[9]
Yan, X. C.; Jia, Y.; Odedairo, T.; Zhao, X. J.; Jin, Z.; Zhu, Z. H.; Yao, X. D. Activated carbon becomes active for oxygen reduction and hydrogen evolution reactions. Chem. Commun. 2016, 52, 8156-8159.
[10]
Zhang, S.; Kang, P.; Ubnoske, S.; Brennaman, M. K.; Song, N.; House, R. L.; Glass, J. T.; Meyer, T. J. Polyethylenimine-enhanced electrocatalytic reduction of CO2 to formate at nitrogen-doped carbon nanomaterials. J. Am. Chem. Soc. 2014, 136, 7845-7848.
[11]
Wang, H. X.; Chen, Y. B.; Hou, X. L.; Ma, C. Y.; Tan, T. W. Nitrogen-doped graphenes as efficient electrocatalysts for the selective reduction of carbon dioxide to formate in aqueous solution. Green Chem. 2016, 18, 3250-3256.
[12]
Kuang, M.; Guan, A. X.; Gu, Z. X.; Han, P.; Qian, L. P.; Zheng, G. F. Enhanced N-doping in mesoporous carbon for efficient electrocatalytic CO2 conversion. Nano Res. 2019, 12, 2324-2329.
[13]
Wu, J. J.; Ma, S. C.; Sun, J.; Gold, J. I.; Tiwary, C. S.; Kim, B.; Zhu, L. Y.; Chopra, N.; Odeh, I. N.; Vajtai, R. et al. A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates. Nat. Commun. 2016, 7, 13869.
[14]
Cui, X. Q.; Pan, Z. Y.; Zhang, L. J.; Peng, H. S.; Zheng, G. F. Selective etching of nitrogen-doped carbon by steam for enhanced electrochemical CO2 reduction. Adv. Energy Mater. 2017, 7, 1701456.
[15]
Ghausi, M. A.; Xie, J. F.; Li, Q. H.; Wang, X. Y.; Yang, R.; Wu, M.; Wang, Y.; Dai, L. CO2 overall splitting by a bifunctional metal-free electrocatalyst. Angew. Chem., Int. Ed. 2018, 57, 13135-13139.
[16]
Chen, Z. P.; Mou, K. W.; Yao, S. Y.; Liu, L. C. Highly selective electrochemical reduction of CO2 to formate on metal-free nitrogen-doped PC61BM. J. Mater. Chem. A 2018, 6, 11236-11243.
[17]
Li, H. Q.; Xiao, N.; Hao, M. Y.; Song, X. D.; Wang, Y. W.; Ji, Y. Q.; Liu, C.; Li, C.; Guo, Z.; Zhang, F. et al. Efficient CO2 electroreduction over pyridinic-N active sites highly exposed on wrinkled porous carbon nanosheets. Chem. Eng. J. 2018, 351, 613-621.
[18]
Tuci, G.; Filippi, J.; Ba, H.; Rossin, A.; Luconi, L.; Pham-Huu, C.; Vizza, F.; Giambastiani, G. How to teach an old dog new (electrochemical) tricks: Aziridine-functionalized CNTs as efficient electrocatalysts for the selective CO2 reduction to CO. J. Mater. Chem. A 2018, 6, 16382-16389.
[19]
Hursán, D.; Samu, A. A.; Janovák, L.; Artyushkova, K.; Asset, T.; Atanassov, P.; Janáky, C. Morphological attributes govern carbon dioxide reduction on N-doped carbon electrodes. Joule 2019, 3, 1719-1733.
[20]
Wang, W.; Shang, L.; Chang, G. J.; Yan, C. Y.; Shi, R.; Zhao, Y. X.; Waterhouse, G. I. N.; Yang, D. J.; Zhang, T. R. Intrinsic carbon-defect-driven electrocatalytic reduction of carbon dioxide. Adv. Mater. 2019, 31, 1808276.
[21]
Jia, Y.; Zhang, L. Z.; Zhuang, L. Z.; Liu, H. L.; Yan, X. C.; Wang, X.; Liu, J. D.; Wang, J. C.; Zheng, Y. R.; Xiao, Z. H. et al. Identification of active sites for acidic oxygen reduction on carbon catalysts with and without nitrogen doping. Nat. Catal. 2019, 2, 688-695.
[22]
Titirici, M. Defects win over pyridinic sites. Nat. Catal. 2019, 2, 642-643.
[23]
Zhu, J. W.; Huang, Y. P.; Mei, W. C.; Zhao, C. Y.; Zhang, C. T.; Zhang, J.; Amiinu, I. S.; Mu, S. C. Effects of intrinsic pentagon defects on electrochemical reactivity of carbon nanomaterials. Angew. Chem., Int. Ed. 2019, 58, 3859-3864.
[24]
Jiang, Y. F.; Yang, L. J.; Sun, T.; Zhao, J.; Lyu, Z. Y.; Zhuo, O.; Wang, X. Z.; Wu, Q.; Ma, J.; Hu, Z. Significant contribution of intrinsic carbon defects to oxygen reduction activity. ACS Catal. 2015, 5, 6707-6712.
[25]
Daiyan, R.; Tan, X.; Chen, R.; Saputera, W. H.; Tahini, H. A.; Lovell, E.; Ng, Y. H.; Smith, S. C.; Dai, L. M.; Lu, X. Y. et al. Electroreduction of CO2 to CO on a mesoporous carbon catalyst with progressively removed nitrogen moieties. ACS Energy Lett. 2018, 3, 2292-2298.
[26]
Li, W. L.; Herkt, B.; Seredych, M.; Bandosz, T. J. Pyridinic-N groups and ultramicropore nanoreactors enhance CO2 electrochemical reduction on porous carbon catalysts. Appl. Catal. B: Environ. 2017, 207, 195-206.
[27]
Li, F. W.; Xue, M. Q.; Knowles, G. P.; Chen, L.; MacFarlane, D. R.; Zhang, J. Porous nitrogen-doped carbon derived from biomass for electrocatalytic reduction of CO2 to CO. Electrochim. Acta 2017, 245, 561-568.
[28]
Lu, M.; Qian, Y. J.; Yang, C. C.; Huang, X.; Li, H.; Xie, X. J.; Huang, L.; Huang, W. Nitrogen-enriched pseudographitic anode derived from silk cocoon with tunable flexibility for microbial fuel cells. Nano Energy 2017, 32, 382-388.
[29]
Cho, S. Y.; Yun, Y. S.; Lee, S.; Jang, D.; Park, K. Y.; Kim, J. K.; Kim, B. H.; Kang, K.; Kaplan, D. L.; Jin, H. J. Carbonization of a stable β-sheet-rich silk protein into a pseudographitic pyroprotein. Nat. Commun. 2015, 6, 7145.
[30]
Jones, F.; Tran, H.; Lindberg, D.; Zhao, L. M.; Hupa, M. Thermal stability of zinc compounds. Energy Fuels 2013, 27, 5663-5669.
[31]
Caturla, F.; Molina-Sabio, M.; Rodríguez-Reinoso, F. Preparation of activated carbon by chemical activation with ZnCl2. Carbon 1991, 29, 999-1007.
[32]
Liu, S.; Yang, H. B.; Huang, X.; Liu, L. H.; Cai, W. Z.; Gao, J. J.; Li, X. N.; Zhang, T.; Huang, Y. Q.; Liu, B. Identifying active sites of nitrogen-doped carbon materials for the CO2 reduction reaction. Adv. Funct. Mater. 2018, 28, 1800499.
[33]
Won, D. H.; Shin, H.; Koh, J.; Chung, J.; Lee, H. S.; Kim, H.; Woo, S. I. Highly efficient, selective, and stable CO2 electroreduction on a hexagonal Zn catalyst. Angew. Chem., Int. Ed. 2016, 55, 9297-9300.
[34]
Yang, F.; Song, P.; Liu, X. Z.; Mei, B. B.; Xing, W.; Jiang, Z.; Gu, L.; Xu, W. L. Highly efficient CO2 electroreduction on ZnN4-based single-atom catalyst. Angew. Chem., Int. Ed. 2018, 57, 12303-12307.
[35]
Wu, Y. S.; Jiang, J. B.; Weng, Z.; Wang, M. Y.; Broere, D. L. J.; Zhong, Y. R.; Brudvig, G. W.; Feng, Z. X.; Wang, H. L. Electroreduction of CO2 catalyzed by a heterogenized Zn-porphyrin complex with a redox-innocent metal center. ACS Cent. Sci. 2017, 3, 847-852.
[36]
Song, Y. F.; Chen, W.; Zhao, C. C.; Li, S. G.; Wei, W.; Sun, Y. H. Metal-free nitrogen-doped mesoporous carbon for electroreduction of CO2 to ethanol. Angew. Chem., Int. Ed. 2017, 56, 10840-10844.
[37]
Wang, R. M.; Sun, X. H.; Ould-Chikh, S.; Osadchii, D.; Bai, F.; Kapteijn, F.; Gascon, J. Metal-organic-framework-mediated nitrogen-doped carbon for CO2 electrochemical reduction. ACS Appl. Mater. Interfaces 2018, 10, 14751-14758.
[38]
Wang, H.; Jia, J.; Song, P. F.; Wang, Q.; Li, D. B.; Min, S. X.; Qian, C. X.; Wang, L.; Li, Y. F.; Ma, C. et al. Efficient electrocatalytic reduction of CO2 by nitrogen-doped nanoporous carbon/carbon nanotube membranes: A step towards the electrochemical CO2 refinery. Angew. Chem., Int. Ed. 2017, 56, 7847-7852.
[39]
Lee, C. W.; Cho, N. H.; Im, S. W.; Jee, M. S.; Hwang, Y. J.; Min, B. K.; Nam, K. T. New challenges of electrokinetic studies in investigating the reaction mechanism of electrochemical CO2 reduction. J. Mater. Chem. A 2018, 6, 14043-14057.
[40]
Medina-Ramos, J.; DiMeglio, J. L.; Rosenthal, J. Efficient reduction of CO2 to CO with high current density using in situ or ex situ prepared bi-based materials. J. Am. Chem. Soc. 2014, 136, 8361-8367.
[41]
Wuttig, A.; Yoon, Y.; Ryu, J.; Surendranath, Y. Bicarbonate is not a general acid in Au-catalyzed CO2 electroreduction. J. Am. Chem. Soc. 2017, 139, 17109-17113.