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Nano Biomedicine and Engineering 2021, 13(1): 62-71 https://doi.org/10.5101/nbe.v13i1.p62-71
Research Article | Open Access | Issue | Published: 20 January 2021

Aspirin in Food Samples for Separation and Micro Determination of Copper(Ⅱ) Using Cloud Point Extraction/Solvation Method

Show Author's Information Ebaa Adnan Azooz1( ),  Jihan Razzaq Moslim2,  Safa Mageed Hameed2,  Shawket Kadhem Jawad2,  Emad Abbas Jaffar Al-Mulla3( )
The Gifted Students' School in Najaf. The General Directorate of Education Al-Najaf, Ministry of Education, Iraq
Chemistry Department, Faculty of Education for Women, University of Kufa, Al-Najaf, Iraq
Pathological Analysis Techniques, Faculty of Health and Medical Techniques, Al-Furat Al-Awsat Technical University, An-Najaf, Iraq
Keywords:
Copper, Separation, Aspirin, Cloud point extraction, Solvent extraction
Cite this article:
Azooz EA, Moslim JR, Hameed SM, et al. Aspirin in Food Samples for Separation and Micro Determination of Copper(Ⅱ) Using Cloud Point Extraction/Solvation Method. Nano Biomedicine and Engineering, 2021, 13(1): 62-71. https://doi.org/10.5101/nbe.v13i1.p62-71
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Abstract Full text About this article

In this work, sensitive method was used for the first time by joining cloud point extraction with solvation system (CPE-SS) using aspirin as the organic reagent to form cloud point layer (CPL). It had a wavelength for final absorbance under λmax = 293 nm. Different kinds and concentrations of salting out with different extraction efficiencies were used to enhance the extraction efficiency. KNO3 as a salting out under 0.1 M showed maximum extraction efficiency in the presence of 40 μg of Cu(Ⅱ). The applications of extraction in this method had required the existence of 0.4 mL of Triton X-100 and heating under 85 ℃ for 20 minutes to form CPL quantitatively. The effect of different surfactants and various organic reagents to investigate the impact of interferences as well as spectrophotometric determination were also investigated in this study. Chicken, breast, cow meat (beef), cucumber, drainage fish, garden cress and lettuce showed low limit of detection (LOD) 0.018 ppm, limit of quantity (LOQ) 0.060 ppm and RSD% of 0.028 in 2 ppm.


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About this article

Aspirin in Food Samples for Separation and Micro Determination of Copper(Ⅱ) Using Cloud Point Extraction/Solvation Method

Show Author's information Ebaa Adnan Azooz1( ), Jihan Razzaq Moslim2, Safa Mageed Hameed2, Shawket Kadhem Jawad2, Emad Abbas Jaffar Al-Mulla3( )
The Gifted Students' School in Najaf. The General Directorate of Education Al-Najaf, Ministry of Education, Iraq
Chemistry Department, Faculty of Education for Women, University of Kufa, Al-Najaf, Iraq
Pathological Analysis Techniques, Faculty of Health and Medical Techniques, Al-Furat Al-Awsat Technical University, An-Najaf, Iraq

Abstract

In this work, sensitive method was used for the first time by joining cloud point extraction with solvation system (CPE-SS) using aspirin as the organic reagent to form cloud point layer (CPL). It had a wavelength for final absorbance under λmax = 293 nm. Different kinds and concentrations of salting out with different extraction efficiencies were used to enhance the extraction efficiency. KNO3 as a salting out under 0.1 M showed maximum extraction efficiency in the presence of 40 μg of Cu(Ⅱ). The applications of extraction in this method had required the existence of 0.4 mL of Triton X-100 and heating under 85 ℃ for 20 minutes to form CPL quantitatively. The effect of different surfactants and various organic reagents to investigate the impact of interferences as well as spectrophotometric determination were also investigated in this study. Chicken, breast, cow meat (beef), cucumber, drainage fish, garden cress and lettuce showed low limit of detection (LOD) 0.018 ppm, limit of quantity (LOQ) 0.060 ppm and RSD% of 0.028 in 2 ppm.

Keywords: Copper, Separation, Aspirin, Cloud point extraction, Solvent extraction

References(44)

[1]

E.A. Azooz, F.A. Wannas, and S.K. Jawad, Developed cloud point extraction coupled with onium system for separation and determination cobalt in biological samples. Research Journal of Pharmacy and Technology, 2021, 14(2): 594-598.
DOI Google Scholar
[2]

M.M. Radhi, L.A.A. Jawad, Saffron in KCl mediated by glassy carbon electrode using Cyclic voltammetry. Nano Biomedicine and Engineering, 2018, 10(2): 181-185.
DOI Google Scholar
[3]

N.A.B. Ibrahim, I.H.T. Al-Karkhi, et al., Synthesis of palm oil-based fatty methylhydrazide. Research on Chemecal Intermediates, 2013, 39(5): 2133-2139.
DOI Google Scholar
[4]

M. Kaykhaii, E. Ghasemi, Micro-cloud point extraction for preconcentration of aspirin in commercial tablets prior to spectrophotometric determination. Journal of Analytical Chemistry, 2016, 71(8): 844-848.
DOI Google Scholar
[5]

G. Nafisi, B. Sadeghi, and A.P. Yab, Interaction of aspirin and vitamin C with bovine serum albumin. Journal of Photochemistry and Photobiology. B: Biology, 2011, 105: 198-202.
DOI Google Scholar
[6]

S.K. Jawad, S.M. Hameed, and S.A. Hussein, With solvent extraction method, and via new organic reagent 2-(Benzo thiozolyl azo)-4, 5-diphenyl imidazole for spectrophotometric determination of copper (Ⅱ) in different samples. Baghdad Science Journal, 2014, 11(1): 147-157.
DOI Google Scholar
[7]

S. Bahar, R. Zakerian, Determination of copper in human hair and tea samples after dispersive liquid-liquid micro extraction based on solidification of floating organic drop (DLLME-SFO). Journal of Brazilian Chemical Society, 2012, 23(6): 1166-1173.
DOI Google Scholar
[8]

F.A. Wannas, E.A. Azooz, and S.K. Jawad, Liquid ion exchange with spectrophotometric method for separation and determination W(Ⅵ). Journal of Advanced Ressearch And Dynamic Control System, 2019, 11(7): 260-269.
Google Scholar
[9]

Y. Yamini, A. Tamaddon, Solid-phase extraction and spectrophotometric determination of trace amounts of copper in water samples. Talanta, 1999, 49(1): 119-124.
DOI Google Scholar
[10]

V. Hrastný, M. Komárek, Copper determination using ICP-MS with hexapole collision cell. Chemical Papers, 2009, 63(5): 512-519.
DOI Google Scholar
[11]

J. Laghari, Y. Muhammad, and K. Liaquat, Capillary gas chromatographic analysis of pyrrolidine dithiocarbamate metal chelates. Journal of Separation Science, 2007, 30(16): 2727-2732.
DOI Google Scholar
[12]

A.F. Khudhair, M.K. Hassan, Cloud point extraction and determination of trace iron(Ⅲ) in urine samples by spectrophotometry and flame atomic absorption spectrometry. Asian Journal of Chemistry, 2017, 29(12): 2725-2733.
DOI Google Scholar
[13]

J.K. Shawket, R.K. Rana, Cloud point extraction coupled with liquid ion exchange for separation and determination Mn(Ⅶ) in real samples. Research Journal of Pharmacy and Technology, 2019, 12(10): 4861-4866.
DOI Google Scholar
[14]

E.A. Azooz, J.R. Moslim, and S.K. Jawad, Cloud point extraction methodology for separation, extraction and preconcentration of Mn(Ⅶ) coupled with spectroscopy for determination in different samples. Biochemical and Cellular Archives, 2020, 20(1): 2641-2648.
Google Scholar
[15]

S. Shariati, M. Golshekan, Optimization of cloud point extraction of copper with neocuproine from aqueous solutions using taguchi fractional factorial design. Journal of Analytical Chemistry, 2014, 69(3): 248-301.
DOI Google Scholar
[16]

M. Ghaedi, E. Niknam, Application of triton X-100 coated poly vinyl chloride as new solid phase for preconcentration of Fe3+, Cu2+ and Zn2+ ions and their flame atomic absorption spectrometric determinations. Bulletin of the Chemical Society of Ethiopia, 2010, 24(1): 11-20.
DOI Google Scholar
[17]

S.K. Jawad, S.M. Hameed, and S.A. Hussain, Liquid ion exchange application for micro amount separation and determination of Ca(Ⅱ) and Mg(Ⅱ) as anions species with EDTA, Orienal Journal of Chemistry, 2017, 33 (5): 2421-2429.
DOI Google Scholar
[18]

G. Blanchet-Chouinard, D. Larivière, Determination of Pb in environmental samples after cloud point extraction using crown ether. Talanta, 2018, 179: 300-306.
DOI Google Scholar
[19]

S.K. Jawad, E.A. Azooz, New approach for separation, extraction and determination of zinc in different samples using cloud-point extraction coupled with spectrophotometry. FIRE Journal of Science and Technology, 2015, 3: 261-273.
Google Scholar
[20]

J.K. Shawket, M.U. Kadhium, and E.A. Azooz, Separation and spectrophotometric determination of Iron(Ⅲ) and Mercury(Ⅱ) via Cloud point extraction with new Azo-derivative. Eurasian Journal of Analytical Chemistry, 2018, 13(5): 1-11.
DOI Google Scholar
[21]

S.K. Jawad, E.A. Azooz, Cloud point extraction method for separation and pre concentration of Mg(Ⅱ) as anion coupled with spectrophotometric applications. International Journal of Research in Applied, Natural and Social Sciences, 2015, 1(2): 119-133.
Google Scholar
[22]

E.A.J. Al-Mulla, K.W.S. Al-Janabi, Extraction of cobalt(Ⅱ) from aqueous solution by N, N′-carbonyl difatty amides. Chinese Chemical Letters, 2011, 22 (4): 469-472.
DOI Google Scholar
[23]

L. Zhao, S. Zhong, and K. Fang, Determination of cadmium(Ⅱ), cobalt(Ⅱ), nickel(Ⅱ), lead(Ⅱ), zinc(Ⅱ), and copper(Ⅱ) in water samples using dual-cloud point extraction and inductively coupled plasma emission spectrometry. Journal of Hazardous Materials, 2012, 239: 206-212.
DOI Google Scholar
[24]

S. Abbas, Y. Al-Khafaji, and H. Al-Khafaji, Cloud Point Extraction as a Procedure of Separation and Pre-Concentration for Cupper (Ⅱ) Determination Using Spectrofluorometric Techniques. Journal of Pharmaceutical Sciences and Research, 2018, 10 (7): 1748-1752.
Google Scholar
[25]

H. Xu, W. Zhanga, X. Zhangb, et al., Simultaneous preconcentration of cobalt, nickel and copper in water samples by cloud point extraction method and their determination by flame atomic absorption spectrometry. Procedia Environmental Sciences, 2013, 18: 258-263.
DOI Google Scholar
[26]

F. Liu, J. Sun, and B. Jiang, Use of cloud point extraction for removal of nanosized copper oxide from wastewater. Chinese Science Bulletin, 2010, 55: 346-349.
DOI Google Scholar
[27]

J.K. Shawket, M.U. Kadhium, and A.S. Alwan, Incorporation solvation with cloud point extraction method for separation and spectrophotometric determination of Cerium(Ⅲ). Orienal Journal of Chemistry, 2017, 33(4): 1985-1993.
DOI Google Scholar
[28]

S.K. Jawad, M.O. Kadhim, and E.A. Azooz, Incorporation onium system with cloud point extraction method for extraction and determination Iron(Ⅲ) and Mercury(Ⅱ) in different samples, Orienal Journal of Chemistry, 2017, 33(4): 1879-1889.
DOI Google Scholar
[29]

M.M. Radhi, A.I. Ibrahim, and I.A. Mizher, Electrochemical characterization of sky honey mediated by glassy carbon electrode modified with carbon nanotube. Nano Biomedicine and Engineering, 10 (4), 417-422.
DOI Google Scholar
[30]

S.K. Jawad, E.A. Azooz, Cloud point extraction for separation, preconcentration and extraction of Nickel(Ⅱ) as chloroanion by use crown ether DB18C6 coupled with spectrophotometric determination, International Journal of Scientific and Technology Research, 2014, 4(32): 17-23.
DOI Google Scholar
[31]

A. Arain, T. GulKazi, and I. Afridi, A new dispersive liquid-liquid micro extraction using ionic liquid based microemulsion coupled with cloud point extraction for determination of copper in serum and water samples, Ecotoxicology and Environmental Safety, 2016, 126: 186-192.
DOI Google Scholar
[32]

F.A. Wannas, S.K. Jawad, Extraction and determination of Nickel(Ⅱ) via cloud point method. Inter. Journal of Engineering Technology, 2018, 7(4): 725-731.
DOI Google Scholar
[33]

S.K. Jawad, M.U. Kadhium, and E.A. Azooz, Application cloud point extraction method joined with liquid Ion exchange for selective determination of Fe3+ and Hg2+ in real samples. Journal of Engineering and Applied Sciences, 2019, 14(11): 3514-3521.
DOI Google Scholar
[34]

A. Lemos, S. Santos, and X. Baliza, Me-BTABr reagent in cloud point extraction for spectrometric determination of copper in water samples. Journal of the Brazilian Chemical Society, 2006, 17(1): 30-35.
DOI Google Scholar
[35]

J. Chen, K. Teo, Determination of cadmium, copper, lead and zinc in water samples by flame atomic absorption spectrometry after cloud point extraction. Analytica Chimica Acta, 2001, 450(215): 215-222.
DOI Google Scholar
[36]

L. Manzoori, B. Tabrizi, The application of cloud point preconcentration for the determination of Cu in real samples by flame atomic absorption spectrometry. Microchemical Journal, 2002, 72(1): 1-7.
DOI Google Scholar
[37]

A. Tang, D. Jiang, Cloud point extraction preconcentration for capillary electrophoresis of metal ions. Analytica Chimica Acta, 2004, 507(203): 199-204.
DOI Google Scholar
[38]

M. Silva, A. Frescura, Determination of trace elements in water samples by ultrasonic nebulization inductively coupled plasma mass spectrometry after cloud point extraction. Spectrochimica Acta Part B: Atomic Spectroscopy, 2000, 55: 803.
DOI Google Scholar
[39]

M. Shokrollahi, S. Ghaedi, Cloud point extraction for the determination of copper in environmental samples by flame Atomic sbsorption spectrometry. Quimica Nova, 2008, 31(1): 70-74.
DOI Google Scholar
[40]

N. Baghban, A. Shabani, and S. Dadfarnia, Cloud point extraction of trace amounts of copper and its determination by flow injection flame atomic absorption spectrometry. Croatica Chemica Acta, 2012, 85(1): 85-90.
DOI Google Scholar
[41]

M. Ghaedi, A. Shokrollahi, F. Ahmadia, Cloud point extraction for the determination of copper, nickel and cobalt ions in environmental samples by flame atomic absorption spectrometry. Journal of Hazardous Materials, 2008, 150: 533-540.
DOI Google Scholar
[42]

V. Lemos, M. Santos, and G. David, Development of a cloud-point extraction method for copper and nickel determination in food samples. Journal of Hazardous Materials, 2008, 159: 245-251.
DOI Google Scholar
[43]

M. Ghaedi, A. Niknamb, and E. Niknama, Development of efficient method for preconcentration and determination of Copper, Nickel, Zinc and Iron ions in environmental samples by combination of cloud point extraction and flame atomic absorption spectrometry. Central European Journal of Chemistry, 2009, 7(1): 148-154.
DOI Google Scholar
[44]

P. Biparva, M. Hadjmohammadi, Cloud point extraction using NDTT reagent for preconcentration and determination of copper in some environmental water Samples by flame atomic absorption spectroscopy. Acta Chimica Slovenica, 2007, 54: 805-810.
Google Scholar
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Publication history

Received: 16 June 2020
Accepted: 27 October 2020
Published: 20 January 2021
Issue date: March 2021

Copyright

© Ebaa Adnan Azooz, Jihan Razzaq Moslim, Safa Mageed Hameed, Shawket Kadhem Jawad, and Emad Abbas Jaffar Al-Mulla.

Acknowledgements

The analysis in the advanced analytical Laboratory of Chemistry Department Faculty of Education for Women University of Kufa is exceedingly acknowledged.

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This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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