Copper Metal at New CuO Nanoparticles Modified Carbonpaste Electrode: Selective Voltammetric Determination

Amer Mousa Jouda; Emad Salaam Abood; Mothana Salih Mashloor

doi:10.5101/nbe.v10i3.p243-249

Nano Biomedicine and Engineering 2018, 10(3): 243-249 https://doi.org/10.5101/nbe.v10i3.p243-249

Research Article |

Open Access | Issue | Published: 20 August 2018

Copper Metal at New CuO Nanoparticles Modified Carbonpaste Electrode: Selective Voltammetric Determination

Show Author's Information Hide Author's Information Amer Mousa Jouda, Emad Salaam Abood(

), Mothana Salih Mashloor

Department of Chemistry, Faculty of Science, University of Kufa, 54001 AnNajaf, Iraq

Keywords:

Nanoparticles, Cyclic voltammetry, Electrodes

Cite this article:

Jouda AM, Abood ES, Mashloor MS. Copper Metal at New CuO Nanoparticles Modified Carbonpaste Electrode: Selective Voltammetric Determination. Nano Biomedicine and Engineering, 2018, 10(3): 243-249. https://doi.org/10.5101/nbe.v10i3.p243-249

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Abstract

A new carbon paste electrode modified with CuO nanoparticles was prepared, and used to study the electro oxidation of copper ions in solution by cyclic voltammetry (CV) method. The modified electrode displayed strong resolving function for the overlapping voltammetric response of copper into one well-defined peak. The potential difference between Epa and Epc was > 200 mV; this range referred to the quise-reversible mechanism. The kinetic of electrode was studied at the temperature range from 15 ~ 35 °C; the data of voltamograms showed the increase of temperature caused increase of negative shift, which suggested the diffusion electron transfer in the redox process of copper oxidation. Diffusion coefficient was calculated from the Randles-Sevcik equation and was equal to 71.8 × 10^-4; the rate constant K was equal to 8.8 × 10^-7; the peak current of copper increased linearly with its concentration at the range of 0.2 ~ 2.0 ppm.

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Copper Metal at New CuO Nanoparticles Modified Carbonpaste Electrode: Selective Voltammetric Determination

Show Author's information Hide Author's Information Amer Mousa Jouda, Emad Salaam Abood(

), Mothana Salih Mashloor

Department of Chemistry, Faculty of Science, University of Kufa, 54001 AnNajaf, Iraq

Abstract

Keywords: Nanoparticles, Cyclic voltammetry, Electrodes

References(20)

[1]

W.A. Banks, Cell-mediated immune response to human papillomavirus infection. Clin Diagn Lab Immunal, 2001, 8: 209-220.

DOI Google Scholar

[2]

M.A. Fotopoulou, P.C. Loannou, Simultaneous determination of epinephrine, noradrenaline and dopamine in human serum samples by high performance liquid chromatography with chemiluminescence detection. Chinese Journal of Chemistry, 2002, 25: 942-946.

DOI Google Scholar

[3]

S.L. Wei, G.Q. Song, and J.M. Li, Sensitive determination of epinephrine in pharmaceutical preparation by flow injection coupled with chemiluminescence detection and mechanism study. The Journal of Biological and Chemical Luminescent, 2005, 9: 1098, 166.

Google Scholar

[4]

J.X. Du, L.H. Shen, and J.R. Lu, Cetyltrime thylammonium bromide-enhanced chemiluminescene determination of uric acid using a luminal-hexacyano ferrate (Ⅲ) system. The Japan Society for Analytical Chemistry, 2003, 21: 183.

Google Scholar

[5]

Z. Lin, X. Wu, X. Lin, et al., End-column chemiluminescence detection for pressurized capillary electrochromatographic analysis of norepinephrine and epinephrine. Journal of Chromatography, 2007, 12, (1-2): 118-121.

DOI Google Scholar

[6]

C. Canizares, L. de Castro, Using thermal and spectroscopic data to investigate the thermal behavior of epinephrine. Elsevier Science, 2010, 499: 123-127.

DOI Google Scholar

[7]

M.H. Sorouraddin, J.L. Manzoori., E. Kargarzadeh, et al., Studies on oxidation of noradrenaline using CuPc as catalyst. Advanced Materials Research, 2012, 496: 419-422.

DOI Google Scholar

[8]

Y. Su, J. Wang, and G. Chen, Talanta, Using thermal and spectroscopic data to investigate the thermal behavior of epinephrine. Elsevier, 2005, 65: 531-536.

DOI Google Scholar

[9]

H. Beitollahi, M.M. Aedakani, B. Ganjipour, et al., Carbon nanotubes in electrochemical sensors. Biosens. Bioelectron, 2008, 24: 362.

DOI Google Scholar

[10]

Z. Yang, G. Hu, X. Chen, et al., A review on the synthesis of TiO₂ nanoparticles by solution route. Central European Journal of Chemistry, 2012, 54: 279-294.

DOI Google Scholar

[11]

M. Mazloum-Ardakani, H. Beitollahi, M.A. Sheikh-Mohseni, et al., Electropolymerization of bromothymol blue on carbon paste electrode bulk modified with oxidized multiwall carbon nanotubes and its application in amperometric sensing of epinephrine in pharmaceutical and biological samples. Elsevier, 2012, 732: 30-37.

DOI Google Scholar

[12]

H. Yi, D. Zheng, C. Hu, et al., Functionalized multiwalled carbon nanotubes through in situ electropolymerization of brilliant cresyl blue for determination of epinephrine. Electroanalysis, 2008, 20: 1143.

DOI Google Scholar

[13]

Y. Ishii, M. Iijima, T. Umemura, et al., J. pharm, Determination of nitrotyrosine and tyrosine by high-performance liquid chromatography with tandem mass spectrometry and immunohistochemical analysis in livers of mice administered acetaminophen. Journal pharma Biomed, 2006. 41: 1325.

DOI Google Scholar

[14]

J. Hanaee, Carbon film resistor electrode for amperometric determination of acetaminophen in pharmaceutical formulations. Journal of Pharmaceutical and Biomedical, 2007, 43: 1622-1627.

DOI Google Scholar

[15]

B.O. Regan, M. Gratzel, Synthesis and characterization of metal organic chemical vapour deposited copper titanium oxide (Cu-Ti-O) thin films from single solid source precursors. Journal of Modern Physics, 2013, 4: 12.

Google Scholar

[16]

A. Elkhidir, Y.W. Tang, X. Zhang, et al., Preparation of ZnO nanoparticles and nanosheets and their application to dye-sensitized solar cells. Solar Energy Materials and Solar Cells, 2007, 91: 1658-1660.

DOI Google Scholar

[17]

X. Gao, X. Li, and W. Yu, Low temperature solution synthesis and characterization of ZnO nano-flowers. Materials Research Bulletin, 2007, 42: 1640-1648.

DOI Google Scholar

[18]

J. Zhang, L.D. Sun, C.S. Liao, et al., Synthesis and characterization of MgF₂ and KMgF₃ nanorods. Journal of Solid State Chemistry, 2004, 177: 2205-2207.

DOI Google Scholar

[19]

V. Pandey, S.K. Tripathia, A. Kumar, et al., Linear and nonlinear optical properties of GeSe₂-xSnx (0 ≤ x ≤ 0.8) thin films for optoelectronic applications. Journal of Alloys and Compounds, 2017, 709: 640-645.

DOI Google Scholar

[20]

R.L. Penn, J.F. Banfield, Preparation of ZnO nanoparticles and nanosheets and their application to dye-sensitized solar cells. Journal of Solid State Chemistry, 2007, 91: 1685-1689.

Google Scholar

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Publication history

Received: 05 May 2018

Accepted: 12 July 2018

Published: 20 August 2018

Issue date: September 2018

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This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.