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Taking the eutrophic sediment as the research object, the indoor culture experiment was carried out. From the perspective of environmental micro-interface, the effects of common submerged plant Vallisneria natans on the migration and transformation of As(Ⅲ) and As(Ⅴ) in interstitial water of sediment, the behavior of environmental micro-interface were explored, and the removal effect of Vallisneria natans on As in the sediment-water interface was accurately evaluated. The results showed that Vallisneria natans increased the penetration depth of dissolved oxygen in the sediment and decreased the pH, UV254, dissolved As, As(Ⅴ), As(Ⅲ), dissolved Fe(Ⅱ) and dissolved Mn; three forms of As (dissolved As, As(Ⅴ) and As(Ⅲ)) were significantly correlated with dissolved Mn and UV254, and were poorly correlated with dissolved Fe(Ⅱ); the removal effect of As(Ⅲ) (69.5%) was better than that of As(Ⅴ) (64.6%). The research can provide a scientific basis for the control of heavy metal pollution in sediments and the water ecological restoration.
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