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Communication | Open Access

Fluorescence-active nanorod-like triads assembled from organically-derivatized polyoxometalates

Chun-Lin Lv1,2 ( ), Meng-Yuan Cheng1, Jian Hao2, Nasim Khan Naumaan Rao2, Yongge Wei2 ( )
College of Pharmacy, Minzu University of China, Beijing 100081, China
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
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Abstract

Two monosubstituted organoimido hexamolybdates containing isoquinoline or quinoline were successfully synthesized. Through the coordination driving of silver(I) ions, the obtained organoimido-derivatized hexamolybdates can assemble with β-octamolybdate in a controlled manner to form nanorod-like triads. Unlike the isolated polyoxometalates before assembly, nanosized polyoxometalate assemblies can exhibit interesting fluorescence activities.

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Keywords

polyoxometalatenanorod-like triadsfluorescencecoordinationself-assembly

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Polyoxometalates
Volume 4 Issue 4,
December 2025
Article number: 9140106
DOI: 10.26599/POM.2025.9140106

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Cite this article:
Lv C-L, Cheng M-Y, Hao J, et al. Fluorescence-active nanorod-like triads assembled from organically-derivatized polyoxometalates. Polyoxometalates, 2025, 4(4): 9140106. https://doi.org/10.26599/POM.2025.9140106

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Received: 29 October 2025
Revised: 03 December 2025
Accepted: 04 December 2025
Published: 23 December 2025
© The Author(s) 2025. Published by Tsinghua University Press.

Open Access This article is licensed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, sharing, distribution and reproduction in any medium, provided the original work is properly cited.