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Review Article | Open Access

Overview of organophosphonate covalently modified polyoxometalates: From synthesis and structural diversity to applications

Hui Kong1,2 , Pengtao Ma1 , Jingping Wang1 ( ), Jingyang Niu1 ( )
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
College of Chemistry and Pharmaceutical Engineering, Huanghuai University, Zhumadian 463000, China
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Abstract

In the field of polyoxometalate (POM) chemistry, organophosphonate covalently modified polyoxometalates (OCMPs) have recently emerged as a promising frontier. These hybrid materials not only broaden the structural diversity of conventional POM derivatives and address the inherent stability limitations of POMs, but also allow for the design of improved properties tailored to diverse applications. Despite this growing interest, a systematic review dedicated to OCMPs is still lacking. This review provides a comprehensive summary of recent advances in OCMP research, with a particular focus on their structural features, functional properties, and prospective research directions.

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Keywords

organophosphonate covalently modified polyoxometalatesorganophosphonic acidsphotochromismmagnetizationcatalysis

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Polyoxometalates
Volume 4 Issue 4,
December 2025
Article number: 9140103
DOI: 10.26599/POM.2025.9140103

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Cite this article:
Kong H, Ma P, Wang J, et al. Overview of organophosphonate covalently modified polyoxometalates: From synthesis and structural diversity to applications. Polyoxometalates, 2025, 4(4): 9140103. https://doi.org/10.26599/POM.2025.9140103

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Received: 16 May 2025
Revised: 18 September 2025
Accepted: 23 September 2025
Published: 19 October 2025
© The Author(s) 2025. Published by Tsinghua University Press.

Open Access This article is licensed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, sharing, distribution and reproduction in any medium, provided the original work is properly cited.