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Review Article | Open Access

Ruthenium containing polyoxometalates: From synthesis, structures, properties to functional applications

Qingmiao Cai1 , Ruili Gao1, Yanfei Wang1, Jiashen Xing1, Qingyang Zhang1, Muzi Zhu1, Xinyuan Qin1, Meihong Liao2, Yichao Huang1 ( )
State Key Laboratory of Chemical Safety, School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China
School of Mechanical and Electronic Engineering, Qingdao Binhai University, Qingdao 266555, China
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Abstract

Ruthenium-containing polyoxometalates (Ru-POMs) are a class of heteropolyanions (vanadates, molybdates, or tungstates) containing at least one Ru atom as a heteroatom or “addenda” atom. In recent years, Ru-POMs have attracted considerable attention owing to their structural versatility, intriguing redox properties, and oxidation resistance, rendering them highly promising for applications in organocatalysis, electrocatalysis, photocatalysis, and beyond. This review summarizes the advances in Ru-POMs, covering their synthesis methods, structures, properties, and applications. It aims to serve as a reference and guide for the future design and development of novel Ru-POM structures and applications.

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Keywords

rutheniumpolyoxometalatesorganocatalysiselectrocatalysisphotocatalysis

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Polyoxometalates
Volume 4 Issue 2,
June 2025
Article number: 9140083
DOI: 10.26599/POM.2024.9140083

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Cite this article:
Cai Q, Gao R, Wang Y, et al. Ruthenium containing polyoxometalates: From synthesis, structures, properties to functional applications. Polyoxometalates, 2025, 4(2): 9140083. https://doi.org/10.26599/POM.2024.9140083

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Received: 10 October 2024
Revised: 03 December 2024
Accepted: 13 December 2024
Published: 06 January 2025
© The Author(s) 2025. Published by Tsinghua University Press.

Open Access This article is licensed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, sharing, distribution and reproduction in any medium, provided the original work is properly cited.