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Communication | Open Access

Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate

Fengping Xiao1,2 ( ), Xianggao Meng1, Longsheng Wang2,3, Jian Hao2, Chunlin Lv2, Yongge Wei2 ( )
College of Chemistry, Central China Normal University, Wuhan 430079, China
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
School of Material and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China
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Abstract

Using chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2(CH2OCH2)nCH2OC6H4-o)N] (compounds 1, n = 1; 2, n = 2). As confirmed by single-crystal X-ray diffraction and infrared (IR) studies, the polyoxometalatocrown ether 2 can capture primary ammonium cations in solid state.

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Keywords

polyoxometalatescrown etherscrystal structureorganic ammonium cations

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Polyoxometalates
Volume 3 Issue 2,
June 2024
Article number: 9140055
DOI: 10.26599/POM.2024.9140055

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Cite this article:
Xiao F, Meng X, Wang L, et al. Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate. Polyoxometalates, 2024, 3(2): 9140055. https://doi.org/10.26599/POM.2024.9140055

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Received: 26 October 2023
Revised: 23 December 2023
Accepted: 08 January 2024
Published: 19 January 2024
© The Author(s) 2024. Published by Tsinghua University Press.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0), which permits reusers to distribute, remix, adapt, and build upon the material in any medium or format, so long as attribution is given to the original author(s) and the source, provide a link to the license, and indicate if changes were made. See http://creativecommons.org/licenses/by/4.0/