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Polyoxometalates 2024, 3(1): 9140048 https://doi.org/10.26599/POM.2023.9140048
Review Article | Open Access | Issue | Published: 22 December 2023

Polyoxometalate catalysts for the synthesis of N-heterocycles

Show Author's Information Qilong Hu,  Ke Li,  Xuejiao Chen,  Yufeng Liu ( ),  Guoping Yang( )
Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, School of Chemistry and Material Science, East China University of Technology, Nanchang 330013, China
Keywords:
catalysis, N-heterocycles, polyoxometalates, organic transformation
Cite this article:
Hu Q, Li K, Chen X, et al. Polyoxometalate catalysts for the synthesis of N-heterocycles. Polyoxometalates, 2024, 3(1): 9140048. https://doi.org/10.26599/POM.2023.9140048
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Abstract Full text About this article

N-Heterocycle compounds are crucial scaffolds in natural products, synthetic molecules, agricultural chemicals, and pharmaceuticals. Hence, green catalytic systems for the synthesis of N-heterocycles have been widely researched in organic synthesis and industrial catalysis. Polyoxometalates (POMs) are polynuclear metal–oxygen clusters with diverse structures and physicochemical properties. POMs exhibit multiple advantageous properties such as adjustable acidity, redox properties, high thermal stability, and nontoxic nature. Therefore, POMs have been widely investigated for their application in N-heterocycles synthesis and held great potential for industrial applications. In this review, we summarize recent advances (mainly from 2010 to 2023) in the synthesis of N-heterocycles, such as pyrroles, indoles, pyridines, and benzodiazepines, catalyzed by heteropolyacids (HPAs), modified HPA catalysts, and transition metal-modified POMs. The prospects of POM-based catalytic systems for the synthesis of N-heterocycles are also outlined.


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About this article

Polyoxometalate catalysts for the synthesis of N-heterocycles

Show Author's information Qilong Hu, Ke Li, Xuejiao Chen, Yufeng Liu ( ), Guoping Yang( )
Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, School of Chemistry and Material Science, East China University of Technology, Nanchang 330013, China

Abstract

N-Heterocycle compounds are crucial scaffolds in natural products, synthetic molecules, agricultural chemicals, and pharmaceuticals. Hence, green catalytic systems for the synthesis of N-heterocycles have been widely researched in organic synthesis and industrial catalysis. Polyoxometalates (POMs) are polynuclear metal–oxygen clusters with diverse structures and physicochemical properties. POMs exhibit multiple advantageous properties such as adjustable acidity, redox properties, high thermal stability, and nontoxic nature. Therefore, POMs have been widely investigated for their application in N-heterocycles synthesis and held great potential for industrial applications. In this review, we summarize recent advances (mainly from 2010 to 2023) in the synthesis of N-heterocycles, such as pyrroles, indoles, pyridines, and benzodiazepines, catalyzed by heteropolyacids (HPAs), modified HPA catalysts, and transition metal-modified POMs. The prospects of POM-based catalytic systems for the synthesis of N-heterocycles are also outlined.

Keywords: catalysis, N-heterocycles, polyoxometalates, organic transformation

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Publication history

Received: 14 September 2023
Revised: 24 November 2023
Accepted: 27 November 2023
Published: 22 December 2023
Issue date: March 2024

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© The Author(s) 2023. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 22001034) and Jiangxi Provincial Natural Science Foundation (No. 20212BAB213001).

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