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Review Article | Open Access

Supramolecular self-assembly of polyoxometalates and cyclodextrin: Progress and perspectives

Pai Wang1,§, Zitong Wang1,§, Peisen Wang1, Aadil Nabi Chishti1, Hongxu Zhang1, Jianhang Shi1, Lubin Ni1 ( ), Saba Jamil3 ( ), Yongge Wei2 ( )
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
Department of Chemistry, University of Agriculture, Faisalabad 38000, Pakistan

§ Pai Wang and Zitong Wang contributed equally to this work.

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Abstract

In this study, we present a comprehensive overview of supramolecular self-assemblies comprising cyclodextrins (CDs) and polyoxometalates (POMs). We summarize the recent advancements in supramolecular POM–CD systems, including their structures, functions, and applications. Subsequently, we focus on the self-assembly behavior of CDs and POMs, encompassing the formation of inclusion complexes, host–guest interactions, and the development of hybrid materials. In addition, we discuss the remarks on future outlooks and hope that this review will serve as a valuable reference for researchers engaged in the fields of supramolecular/POM chemistry, materials science, and nanotechnology.

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Keywords

cyclodextrinspolyoxometalatesself-assemblyhost–guest interaction

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Polyoxometalates
Volume 3 Issue 2,
June 2024
Article number: 9140047
DOI: 10.26599/POM.2023.9140047

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Cite this article:
Wang P, Wang Z, Wang P, et al. Supramolecular self-assembly of polyoxometalates and cyclodextrin: Progress and perspectives. Polyoxometalates, 2024, 3(2): 9140047. https://doi.org/10.26599/POM.2023.9140047

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Received: 21 September 2023
Revised: 19 November 2023
Accepted: 26 November 2023
Published: 04 January 2024
© The Author(s) 2024. Published by Tsinghua University Press.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0), which permits reusers to distribute, remix, adapt, and build upon the material in any medium or format, so long as attribution is given to the original author(s) and the source, provide a link to the license, and indicate if changes were made. See http://creativecommons.org/licenses/by/4.0/