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Polyoxometalates 2024, 3(1): 9140046 https://doi.org/10.26599/POM.2023.9140046
Research Article | Open Access | Issue | Published: 18 December 2023

Chiral polyoxometalate–cyclodextrin frameworks via Mn-mediated assembly: Enhanced stability and catalytic activity

Show Author's Information Xiu-Xia Ding,§,  Yun-Yue Yuan,§,  Ya-Ge Zhang,  Zhan-Guo Jiang ( ),  Cai-Hong Zhan ( )
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China

§ Xiu-Xia Ding and Yun-Yue Yuan contributed equally to this work.

Keywords:
catalysis, chirality, cyclodextrin, polyoxometalate
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Ding X-X, Yuan Y-Y, Zhang Y-G, et al. Chiral polyoxometalate–cyclodextrin frameworks via Mn-mediated assembly: Enhanced stability and catalytic activity. Polyoxometalates, 2024, 3(1): 9140046. https://doi.org/10.26599/POM.2023.9140046
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Abstract Full text Electronic supplementary material About this article

The application of polyoxometalate (POM) as building blocks to construct chiral POM-based functionalized frameworks remains a long-standing challenge. In this study, we report a chiral assembly by blending inorganic POMs and organic cyclodextrin (α-CD) molecules on the basis of coordination interactions. {SiW12} anions connect with Mn ions (Mn2+) antiparallel to form a unique all-inorganic layer with significant voids. The similar α-CD layered structure fills the voids of the POM–Mn layers, which are interwoven to form an organic–inorganic hybrid, which is extended by Na+ ions to produce a three-dimensional framework. The stability, chiral separation, chiral catalysis, and proton conductivity of this composite framework are explored.


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About this article

Chiral polyoxometalate–cyclodextrin frameworks via Mn-mediated assembly: Enhanced stability and catalytic activity

Show Author's information Xiu-Xia Ding,§, Yun-Yue Yuan,§, Ya-Ge Zhang, Zhan-Guo Jiang ( ), Cai-Hong Zhan ( )
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, China

§ Xiu-Xia Ding and Yun-Yue Yuan contributed equally to this work.

Abstract

The application of polyoxometalate (POM) as building blocks to construct chiral POM-based functionalized frameworks remains a long-standing challenge. In this study, we report a chiral assembly by blending inorganic POMs and organic cyclodextrin (α-CD) molecules on the basis of coordination interactions. {SiW12} anions connect with Mn ions (Mn2+) antiparallel to form a unique all-inorganic layer with significant voids. The similar α-CD layered structure fills the voids of the POM–Mn layers, which are interwoven to form an organic–inorganic hybrid, which is extended by Na+ ions to produce a three-dimensional framework. The stability, chiral separation, chiral catalysis, and proton conductivity of this composite framework are explored.

Keywords: catalysis, chirality, cyclodextrin, polyoxometalate

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Publication history

Received: 26 August 2023
Revised: 04 November 2023
Accepted: 22 November 2023
Published: 18 December 2023
Issue date: March 2024

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© The Author(s) 2023. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

We thank the support of this work by the National Natural Science Foundation of China (No. 21801226), Natural Science Foundation of Zhejiang Province (Nos. LY20B010002 and LQ22B010002), and Zhejiang Normal University Fund.

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