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Mini Review | Open Access

Advances in coinage-metal-substituted polyoxometalates: A review

De-Qing QianYu-Diao LinHui-Ping XiaoBiao WuXin-Xiong Li ( )Shou-Tian Zheng ( )
Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fuzhou 350108, China
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Abstract

The introduction of coinage metals (CMs) into lacunary polyoxometalates (POMs) to construct CM-substituted POMs (CM-POMs) has attracted increasing interest over the past decade. This is because CM-POMs combine the unique structural features of POMs and CMs and have promising applications in photocatalysis, luminescence, magnetic materials, etc. In this review, the structural characteristics, synthesis methods, and applications of CM-POMs are summarized in three categories according to the type of their metal core element: Cu-, Ag-, and Au-substituted POMs. Furthermore, this paper discusses the current challenges regarding investigations into the design and properties of CM-POMs.

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Polyoxometalates
Article number: 9140040
Cite this article:
Qian D-Q, Lin Y-D, Xiao H-P, et al. Advances in coinage-metal-substituted polyoxometalates: A review. Polyoxometalates, 2024, 3(1): 9140040. https://doi.org/10.26599/POM.2023.9140040

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Received: 06 August 2023
Revised: 15 September 2023
Accepted: 28 September 2023
Published: 06 November 2023
© The Author(s) 2023. Published by Tsinghua University Press.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0), which permits reusers to distribute, remix, adapt, and build upon the material in any medium or format, so long as attribution is given to the original author(s) and the source, provide a link to the license, and indicate if changes were made. See http://creativecommons.org/licenses/by/4.0/

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