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Design and synthesis of novel polyoxometalate-based binary and ternary nanohybrids for energy conversion and storage
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Guangjin Zhang1,4,5
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Polyoxometalate (POM)-based binary and ternary hybrids, including combinations of POMs, semiconductors, nanostructured carbon (carbon nanotubes, graphene, carbon dots, etc.), and metal nanoparticles (MNPs), are key materials in photoelectrocatalysis. POM plays a key role in the construction of nanohybrids and contributes to their photoelectrochemical catalytic properties. These composites combine the properties of two or three functional nanoscale materials, resulting in a wide range of applications, including catalysis, energy conversion and storage, molecular sensors, and electronics. Herein, we summarize the latest progress in POM-based binary nanohybrids (POM/metal, POM/semiconductor, and POM/nanocarbon) and ternary nanohybrids (metal/POM/nanocarbon), particularly in energy materials for photocatalysis, fuel cells, biosensors, and photoelectrochemical devices. Current applications are critically assessed, and promising target systems are discussed.
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Design and synthesis of novel polyoxometalate-based binary and ternary nanohybrids for energy conversion and storage
(
), Guangjin Zhang1,4,5
(
)
Abstract
Polyoxometalate (POM)-based binary and ternary hybrids, including combinations of POMs, semiconductors, nanostructured carbon (carbon nanotubes, graphene, carbon dots, etc.), and metal nanoparticles (MNPs), are key materials in photoelectrocatalysis. POM plays a key role in the construction of nanohybrids and contributes to their photoelectrochemical catalytic properties. These composites combine the properties of two or three functional nanoscale materials, resulting in a wide range of applications, including catalysis, energy conversion and storage, molecular sensors, and electronics. Herein, we summarize the latest progress in POM-based binary nanohybrids (POM/metal, POM/semiconductor, and POM/nanocarbon) and ternary nanohybrids (metal/POM/nanocarbon), particularly in energy materials for photocatalysis, fuel cells, biosensors, and photoelectrochemical devices. Current applications are critically assessed, and promising target systems are discussed.
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Acknowledgements
This work is supported by the National Natural Science Foundation of China (Nos. 22178361 and 22378402), the International Partnership Project of Chinese Academy of Sciences (No. 039GJHZ2022029GC), the Deutsche Forschungsgemeinschaft DFG (TRR 234 “CataLight”, grant no: 364549901) and the European Research Council ERC (project “SupraVox”, grant no: 101002212). R. J. L. acknowledges the Alexander-von-Humboldt-Foundation for a postdoctoral fellowship.
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