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12 September 2023
Structural extension of 2D complexes to 3D complexes and their applications
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Two-dimensional (2D) Cu-CP (Cu-CP = [Cu(pca)2∙Hpca]n) (1) with an interpenetrating double-layer structure was prepared using a hydrothermal method based on 4-picolinic acid (Hpca) ligand. Because 3d–4f metal-incorporated polyoxometalate (POM) materials have received increasing attention, the extension of Cu-CP from a 2D to a three-dimensional (3D) structure was achieved by adding H4SiW12O40 and rare earth metal. Three isostructural 3D 3d–4f metal-incorporated POMs were obtained: Cu-Ln-CPs (Cu-Ln-CPs = [Ln2Cu (SiW12O40) (Hpca)4(pca)4(H2O)2]∙(Hpca)2∙(I2)0.5, Ln = Sm (2), Gd (3), La (4)). The applications of these complexes in the fields of fluorescence and electrochemistry were explored. The results showed that the expanded structure of the complexes can realize the fluorescent sensing of Ni2+ and Cr3+ and the electrochemical sensing of nitrite.
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Structural extension of 2D complexes to 3D complexes and their applications
Abstract
Two-dimensional (2D) Cu-CP (Cu-CP = [Cu(pca)2∙Hpca]n) (1) with an interpenetrating double-layer structure was prepared using a hydrothermal method based on 4-picolinic acid (Hpca) ligand. Because 3d–4f metal-incorporated polyoxometalate (POM) materials have received increasing attention, the extension of Cu-CP from a 2D to a three-dimensional (3D) structure was achieved by adding H4SiW12O40 and rare earth metal. Three isostructural 3D 3d–4f metal-incorporated POMs were obtained: Cu-Ln-CPs (Cu-Ln-CPs = [Ln2Cu (SiW12O40) (Hpca)4(pca)4(H2O)2]∙(Hpca)2∙(I2)0.5, Ln = Sm (2), Gd (3), La (4)). The applications of these complexes in the fields of fluorescence and electrochemistry were explored. The results showed that the expanded structure of the complexes can realize the fluorescent sensing of Ni2+ and Cr3+ and the electrochemical sensing of nitrite.
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Acknowledgements
The authors gratefully acknowledge the National Natural Science Foundation of China (Nos. 21671138 and U1608224), the Distinguished Professor Project of Liaoning Province, the General Fund of the Education Department Project of Liaoning Province (No. LJKZ0315), Youth Fund of the University of Science and Technology Liaoning (No. 2020QN04), and Undergraduate Entrepreneurship and Innovation Project of the University of Science and Technology Liaoning (No. X202210146193).
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