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Research Article | Open Access

[MoO4]2−-templated D4h-symmetric sandwich Ag13 nanocluster coprotected with thiolate and phosphine

Jin-Ping Gao1, Zhikai Qi1, Fu-Qiang Zhang1, Xian-Ming Zhang1,2 ( )
Key Laboratory of Magnetic Molecules & Magnetic Information Materials (Ministry of Education), School of Chemistry & Material Science, Shanxi Normal University, Taiyuan 030032, China
College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, China
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Abstract

Mixed-ligand and anion-templated strategies in constructing metal nanoclusters are intricate and ingenious processes that face challenges to be studied. Herein, we report a cationic [Ag13(MoO4)4(SC6H4iPr)2(dppp)8]3+ (Ag13) nanocluster, which is templated using four [MoO4]2− anions and coprotected by 4-isopropylphenol (iPrC6H4S−) and 1,3-bis (diphenylphosphino) propane (dppp). Two capped (Ag4SC6H4iPr)2 units connect with the middle Ag@Ag4 layer via four [MoO4]2− anion templates to form a three-layer D4h-symmetric structure. An ideal crystallographic fourfold axis passes through the central Ag atom and the S and C atoms of the iPrC6H4S− ligand. The layer stacking generates a nonface-centered cubic (nonFCC) structure. The structure and composition of the Ag13 nanocluster have been fully characterized. In addition, the solid ultraviolet–visible (UV–vis) spectra show that Ag13 is a potential narrow-band-gap semiconductor. The photoluminescence (PL) of orange-yellow-light emission is attributed to ligand-to-metal charge transfer. This work has advanced the research on shell engineering of anionic templates and coprotection to assemble high-symmetric Ag nanoclusters.

Keywords

anion-templated[MoO4]2−coprotectedAg(I) nanocluster

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Polyoxometalates
Volume 2 Issue 2,
June 2023
Article number: 9140028
DOI: 10.26599/POM.2023.9140028
Cite this article:
Gao J-P, Qi Z, Zhang F-Q, et al. [MoO4]2−-templated D4h-symmetric sandwich Ag13 nanocluster coprotected with thiolate and phosphine. Polyoxometalates, 2023, 2(2): 9140028. https://doi.org/10.26599/POM.2023.9140028

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Received: 01 March 2023
Revised: 24 April 2023
Accepted: 30 April 2023
Published: 11 May 2023
© The Author(s) 2023. Polyoxometalates published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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