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Polyoxometalates 2022, 1(2): 9140011 https://doi.org/10.26599/POM.2022.9140011
Review Article | Open Access | Issue | Published: 22 November 2022

Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials

Show Author's Information Huaiying Zhang§,  Wan-Lei Zhao§,  Hongqiang Li,  Qinghe Zhuang,  Zeqian Sun,  Dongyuan Cui,  Xuejie Chen,  Ao Guo,  Xiang Ji,  Sai An( ),  Wei Chen,  Yu-Fei Song( )
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

§ Huaiying Zhang and Wan-Lei Zhao contributed equally to this work.

Keywords:
catalysis, photochemistry, electrochemistry, polyoxometalates, covalent modification, molecular assembly, biological application
Cite this article:
Zhang H, Zhao W-L, Li H, et al. Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials. Polyoxometalates, 2022, 1(2): 9140011. https://doi.org/10.26599/POM.2022.9140011
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Abstract Full text About this article

Covalently modified polyoxometalates (POMs), which benefit from the synergistic effect between POMs and covalently grafted moieties, have received increasing attention in various fields. Recent studies on covalently modified POMs mainly focus on function-directed POM assemblies. This review summarizes the latest progress (2017–2022) concerning covalently modified POMs from a functional perspective, which can be classified as assembly chemistry, photochemistry, electrochemistry, homogeneous and heterogeneous catalysis, and biological applications. The roles of POMs and covalently grafted moieties in these hybrids, especially the rational design for specific applications, were considered and emphasized.


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About this article

Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials

Show Author's information Huaiying Zhang§, Wan-Lei Zhao§, Hongqiang Li, Qinghe Zhuang, Zeqian Sun, Dongyuan Cui, Xuejie Chen, Ao Guo, Xiang Ji, Sai An( ), Wei Chen, Yu-Fei Song( )
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

§ Huaiying Zhang and Wan-Lei Zhao contributed equally to this work.

Abstract

Covalently modified polyoxometalates (POMs), which benefit from the synergistic effect between POMs and covalently grafted moieties, have received increasing attention in various fields. Recent studies on covalently modified POMs mainly focus on function-directed POM assemblies. This review summarizes the latest progress (2017–2022) concerning covalently modified POMs from a functional perspective, which can be classified as assembly chemistry, photochemistry, electrochemistry, homogeneous and heterogeneous catalysis, and biological applications. The roles of POMs and covalently grafted moieties in these hybrids, especially the rational design for specific applications, were considered and emphasized.

Keywords: catalysis, photochemistry, electrochemistry, polyoxometalates, covalent modification, molecular assembly, biological application

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Received: 07 July 2022
Revised: 06 October 2022
Accepted: 15 October 2022
Published: 22 November 2022
Issue date: December 2022

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© The Author(s) 2022. Polyoxometalates published by Tsinghua University Press.

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