AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Polyoxometalates Article
PDF (6.9 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property

Rui-Yan Chen, Yan-Ping He ( ), Jian Zhang ( )
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
Show Author Information

Abstract

Herein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating titanium cages and lead-oxo clusters into a rigid cage-cluster-based framework significantly enhances its third-order nonlinear optical (NLO) property.

Graphical Abstract

Keywords

cage-cluster-based frameworktitanium cagemultistage assemblynonlinear optics

Electronic Supplementary Material

Download File(s)
0002_ESM.pdf (581 KB)
0002_ESM_PTC-290.cif (914.8 KB)
0002_ESM_checkcif-PTC-290.pdf (301.8 KB)

References

【1】
【1】
 
 
Crossref Google Scholar
Polyoxometalates
Volume 1 Issue 1,
September 2022
Article number: 9140002
DOI: 10.26599/POM.2022.9140002

{{item.num}}

Comments on this article

Go to comment

< Back to all reports

Review Status: {{reviewData.commendedNum}} Commended , {{reviewData.revisionRequiredNum}} Revision Required , {{reviewData.notCommendedNum}} Not Commended Under Peer Review

Review Comment

Cite this Report
Close
Close
Cite this article:
Chen R-Y, He Y-P, Zhang J. Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property. Polyoxometalates, 2022, 1(1): 9140002. https://doi.org/10.26599/POM.2022.9140002

3713

Views

440

Downloads

18

Crossref

15

Web of Science

17

Scopus
Received: 21 June 2022
Revised: 09 July 2022
Accepted: 29 July 2022
Published: 19 August 2022
© The Author(s) 2022. Polyoxometalates published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.