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Polyoxometalates 2022, 1(1): 9140002 https://doi.org/10.26599/POM.2022.9140002
Research Article | Open Access | Issue | Published: 19 August 2022

Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property

Show Author's Information Rui-Yan Chen,  Yan-Ping He ( ),  Jian Zhang ( )
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
Keywords:
nonlinear optics, cage-cluster-based framework, titanium cage, multistage assembly
Cite this article:
Chen R-Y, He Y-P, Zhang J. Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property. Polyoxometalates, 2022, 1(1): 9140002. https://doi.org/10.26599/POM.2022.9140002
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Abstract Full text Electronic supplementary material About this article

Herein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating titanium cages and lead-oxo clusters into a rigid cage-cluster-based framework significantly enhances its third-order nonlinear optical (NLO) property.


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About this article

Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property

Show Author's information Rui-Yan Chen, Yan-Ping He ( ), Jian Zhang ( )
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Abstract

Herein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating titanium cages and lead-oxo clusters into a rigid cage-cluster-based framework significantly enhances its third-order nonlinear optical (NLO) property.

Keywords: nonlinear optics, cage-cluster-based framework, titanium cage, multistage assembly

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Received: 21 June 2022
Revised: 09 July 2022
Accepted: 29 July 2022
Published: 19 August 2022
Issue date: September 2022

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© The Author(s) 2022. Polyoxometalates published by Tsinghua University Press.

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