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Research Article | Open Access

Using hollow dodecahedral NiCo-LDH with multi-active sites to modify BiVO4 photoanode facilitates the photoelectrochemical water splitting performance

Siwen Feng1Shuyan Fan1Ling Li1Zeyu Sun1Hongwen Tang1Yan Xu1Ling Fang2Cuijuan Wang1( )
School of Chemistry, Southwest Jiaotong University, Chengdu 610031, China
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
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Graphical Abstract

The special hollow dodecahedral structure of HD-NiCo-LDH provides more active sites for the water oxidation reaction. The optimized HD-NiCo-LDH/BiVO4 photoanode has a current density of 4.54 mA/cm2 at 1.23 V vs. RHE.

Abstract

Photoelectrochemical (PEC) water splitting presents a promising approach for harnessing solar energy and converting it into hydrogen energy. However, the limited water oxidation activity of semiconductor photoanodes has severely hampered the overall conversion efficiency. In this study, a hollow dodecahedral structure of NiCo-LDH (HD-NiCo-LDH) was designed using the metal-organic framework ZIF-67 as a precursor. HD-NiCo-LDH was employed to modify the BiVO4 photoanode, serving as an oxygen evolution cocatalyst. HD-NiCo-LDH can enhance light absorption, accelerate photogenic hole extraction, promote photogenic charge separation and improve the kinetics of water oxidation reaction. Significantly, the unique hollow dodecahedral structure of HD-NiCo-LDH possesses a larger specific surface areas, which provides additional active sites for the water oxidation reaction and facilitates the adsorption of water molecules. The photocurrent density of the optimized HD-NiCo-LDH/BiVO4 photoanode reaches 4.54 mA/cm2 at 1.23 V vs. RHE, which is 3.3 times greater than the bare BiVO4 photoanode. This presented work introduces an innovative design concept for photoanodes supported by oxygen evolution cocatalysts with multi-active sites.

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Nano Research Energy
Article number: e9120117
Cite this article:
Feng S, Fan S, Li L, et al. Using hollow dodecahedral NiCo-LDH with multi-active sites to modify BiVO4 photoanode facilitates the photoelectrochemical water splitting performance. Nano Research Energy, 2024, 3: e9120117. https://doi.org/10.26599/NRE.2024.9120117

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Received: 06 December 2023
Revised: 18 January 2024
Accepted: 16 February 2024
Published: 12 March 2024
© The Author(s) 2024. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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