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Nano Research Energy https://doi.org/10.26599/NRE.2024.9120115
Research Article | Open Access | Online first | Published: 01 March 2024

Highly stable Zn anodes realized by 3D zincophilic and hydrophobic interphase buffer layer

Show Author's Information Yunfei Shen1,§,  Pengjie Fu2,§,  Jianjie Liu1,  Kaisheng Sun1,  Huanzhang Wen1,  Ping Liu1,  Heng Lv1,  Tiantian Gu1,  Xiaodong Yang2( ),  Long Chen1( )
School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China
Key Laboratory of Ecophysics and Department of Physics, College of Science, Shihezi University, Shihezi 832003, China

§ Yunfei Shen and Pengjie Fu contributed equally to this work.

Keywords:
heterostructure, hydrophobic, built-in electric field, zinc anode, zincophilic
Cite this article:
Shen Y, Fu P, Liu J, et al. Highly stable Zn anodes realized by 3D zincophilic and hydrophobic interphase buffer layer. Nano Research Energy, 2024, https://doi.org/10.26599/NRE.2024.9120115
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Abstract Full text Electronic supplementary material About this article

Aqueous zinc-ion batteries (AZIBs) are promising contenders for energy storage systems owing to their low cost and high safety. However, their practical application is hindered by uncontrolled Zn dendrites and other side reactions. Here, the three-dimensional (3D) TiO2/Cu2Se/C heterostructure layer derived from MXene/Cu-MOF is constructed on the Zn anode to control the deposition/dissolution behavior, which has numerous active sites, better electrical conductivity and excellent structural stability. Based on DFT calculation, the built-in electric field (BIEF) formed of TiO2/Cu2Se/C can enhance charge transfer and ionic diffusion to inhibit the dendrites. Furthermore, hydrophobic coating has the ability to impede the corrosion and hydrogen evolution reaction (HER) of zinc anode. Thus, TiO2/Cu2Se/C@Zn enable the stable and reversible Zn plating/stripping process with the outstanding lifetime of 1100 h at 2 mA·cm–2 and even 650 h at 10 mA·cm–2. The batteries constructed with commercial MnO2 cathodes demonstrate the remarkable capacity (248.7 mAh·g−1 at 0.1 A·g−1) and impressive cycle stability (with 71.3% capacity retention after 300 cycles). As well as extending the life of AZIBs, this study is also motivating for other metal anode based secondary batteries.


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Electronic supplementary material
About this article

Highly stable Zn anodes realized by 3D zincophilic and hydrophobic interphase buffer layer

Show Author's information Yunfei Shen1,§, Pengjie Fu2,§, Jianjie Liu1, Kaisheng Sun1, Huanzhang Wen1, Ping Liu1, Heng Lv1, Tiantian Gu1, Xiaodong Yang2( ), Long Chen1( )
School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China
Key Laboratory of Ecophysics and Department of Physics, College of Science, Shihezi University, Shihezi 832003, China

§ Yunfei Shen and Pengjie Fu contributed equally to this work.

Abstract

Aqueous zinc-ion batteries (AZIBs) are promising contenders for energy storage systems owing to their low cost and high safety. However, their practical application is hindered by uncontrolled Zn dendrites and other side reactions. Here, the three-dimensional (3D) TiO2/Cu2Se/C heterostructure layer derived from MXene/Cu-MOF is constructed on the Zn anode to control the deposition/dissolution behavior, which has numerous active sites, better electrical conductivity and excellent structural stability. Based on DFT calculation, the built-in electric field (BIEF) formed of TiO2/Cu2Se/C can enhance charge transfer and ionic diffusion to inhibit the dendrites. Furthermore, hydrophobic coating has the ability to impede the corrosion and hydrogen evolution reaction (HER) of zinc anode. Thus, TiO2/Cu2Se/C@Zn enable the stable and reversible Zn plating/stripping process with the outstanding lifetime of 1100 h at 2 mA·cm–2 and even 650 h at 10 mA·cm–2. The batteries constructed with commercial MnO2 cathodes demonstrate the remarkable capacity (248.7 mAh·g−1 at 0.1 A·g−1) and impressive cycle stability (with 71.3% capacity retention after 300 cycles). As well as extending the life of AZIBs, this study is also motivating for other metal anode based secondary batteries.

Keywords: heterostructure, hydrophobic, built-in electric field, zinc anode, zincophilic

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Publication history

Received: 19 December 2023
Revised: 18 January 2024
Accepted: 27 January 2024
Published: 01 March 2024

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© The Author(s) 2024. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

This work is supported by the National Natural Science Foundation of China (Nos. 52302105 and 51962032), the program for Strong Youth Technology Leading Talents (2023CB008-11), the Youth Innovative Top Talents Fund, Shihezi University (CXBJ202203), Youth Science and Technology Innovation Leading Talent Fund, Shihezi (2023RC02), Youth Innovation Promotion Association CAS (2021433). The authors also thank Shiyanjia Lab (www.shiyanjia.com) for the support of XRD, SEM and XPS tests.

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