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Nano Research Energy 2023, 2: e9120077 https://doi.org/10.26599/NRE.2023.9120077
Review Article | Open Access | Issue | Published: 23 May 2023

Recent advances of SiOx-based anodes for sustainable lithium-ion batteries

Show Author's Information Mengyu Zhang1,  Naiwen Liang1,  Derek Hao2,  Zuxin Chen3,4( ),  Fan Zhang1( ),  Jiang Yin1,  Yahui Yang1,  Li-shan Yang1,4( )
Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education of China), National and Local Joint Engineering Laboratory for New Petrochemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, China
School of Science, STEM College, RMIT University, Melbourne 3000, Australia
School of Semiconductor Science and Technology, South China Normal University, Foshan 528225, China
International Iberian Nanotechnology Laboratory (INL), 4715–330 Braga, Portugal
Keywords:
lithium-ion batteries, porous, synthesis methods, SiOx anodes, SiOx/C composites
Cite this article:
Zhang M, Liang N, Hao D, et al. Recent advances of SiOx-based anodes for sustainable lithium-ion batteries. Nano Research Energy, 2023, 2: e9120077. https://doi.org/10.26599/NRE.2023.9120077
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Abstract Full text About this article

The world is facing an ever-growing global energy crisis with unprecedented depth and complexity. The sustainable development of high energy density lithium-ion batteries for electric vehicles and portable electric devices has become a feasible way to deal with this problem. Silicon suboxides (SiOx) have been deemed as one of the most promising anode materials because of their ultrahigh theoretical lithium storage capacity, proper working potential, natural abundance, and environmental friendliness. However, the mass utilization of SiOx-based anodes is severely obstructed by their low electrical conductivity and inevitable volume expansion. While lithium silicate and lithium oxide formed in the first lithiation process act as buffer layers to some extent, it is urgent to address the accompanying low initial Coulombic efficiency and unsatisfactory cycling stability. In this review, we summarized recent advances in the synthesis methods of SiOx-based materials. Besides, the benefits and shortcomings of the various methods are briefly concluded. Then, we discussed the effective combination of SiOx with carbon materials and designs of porous structure, which could considerably enhance the electrochemical performance in detail. Furthermore, progresses on the modified strategies, advanced characteristics and industrial applications for SiOx-based anodes are also mentioned. Finally, the remaining challenges encountered and future perspectives on SiOx-based anodes are highlighted.


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About this article

Recent advances of SiOx-based anodes for sustainable lithium-ion batteries

Show Author's information Mengyu Zhang1, Naiwen Liang1, Derek Hao2, Zuxin Chen3,4( ), Fan Zhang1( ), Jiang Yin1, Yahui Yang1, Li-shan Yang1,4( )
Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education of China), National and Local Joint Engineering Laboratory for New Petrochemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, China
School of Science, STEM College, RMIT University, Melbourne 3000, Australia
School of Semiconductor Science and Technology, South China Normal University, Foshan 528225, China
International Iberian Nanotechnology Laboratory (INL), 4715–330 Braga, Portugal

Abstract

The world is facing an ever-growing global energy crisis with unprecedented depth and complexity. The sustainable development of high energy density lithium-ion batteries for electric vehicles and portable electric devices has become a feasible way to deal with this problem. Silicon suboxides (SiOx) have been deemed as one of the most promising anode materials because of their ultrahigh theoretical lithium storage capacity, proper working potential, natural abundance, and environmental friendliness. However, the mass utilization of SiOx-based anodes is severely obstructed by their low electrical conductivity and inevitable volume expansion. While lithium silicate and lithium oxide formed in the first lithiation process act as buffer layers to some extent, it is urgent to address the accompanying low initial Coulombic efficiency and unsatisfactory cycling stability. In this review, we summarized recent advances in the synthesis methods of SiOx-based materials. Besides, the benefits and shortcomings of the various methods are briefly concluded. Then, we discussed the effective combination of SiOx with carbon materials and designs of porous structure, which could considerably enhance the electrochemical performance in detail. Furthermore, progresses on the modified strategies, advanced characteristics and industrial applications for SiOx-based anodes are also mentioned. Finally, the remaining challenges encountered and future perspectives on SiOx-based anodes are highlighted.

Keywords: lithium-ion batteries, porous, synthesis methods, SiOx anodes, SiOx/C composites

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Publication history

Received: 22 March 2023
Revised: 24 April 2023
Accepted: 03 May 2023
Published: 23 May 2023
Issue date: September 2023

Copyright

© The Author(s) 2023. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

This work was supported partially by the National Key Research and Development Program (No. 2022YFC3900905), the National Natural Science Foundation of China (Nos. 52234001, 62104703, and 52074119), the Science and Technology Planning Project of Hunan Province (No. 2018TP1017), the Scientific Research Fund of Hunan Provincial Education Department (No. 22A0045), the Science and Technology Innovation Program of Hunan Province (No. 2021RC1003), the Changsha Science and Technology Foundation (No. kq2208162) and Joint Funds of Hunan Provincial Innovation Foundation for Post-graduate (No. CX20220512).

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