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Nano Research Energy 2023, 2: e9120048 https://doi.org/10.26599/NRE.2023.9120048
Review Article | Open Access | Issue | Published: 06 January 2023

Present and future of functionalized Cu current collectors for stabilizing lithium metal anodes

Show Author's Information Yuhang Liu1,§,  Yifan Li1,§,  Jinmeng Sun1,  Zhuzhu Du1,  Xiaoqi Hu1,  Jingxuan Bi1,  Chuntai Liu4,  Wei Ai1( ),  Qingyu Yan2,3( )
Frontiers Science Center for Flexible Electronics (FSCFE) & Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi'an 710072, China
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798 Singapore
Institute of Materials Research and Engineering, A*STAR, 138634 Singapore
Key Laboratory of Materials Processing and Mold Ministry of Education, Zhengzhou University, Zhengzhou 450002, China

§ Yuhang Liu and Yifan Li contributed equally to this work.

Keywords:
functionalization, Li metal batteries, Cu current collectors, lithiophilic modification, Li plating/stripping
Cite this article:
Liu Y, Li Y, Sun J, et al. Present and future of functionalized Cu current collectors for stabilizing lithium metal anodes. Nano Research Energy, 2023, 2: e9120048. https://doi.org/10.26599/NRE.2023.9120048
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Abstract Full text About this article

Li metal has been recognized as the most promising anode materials for next-generation high-energy-density batteries, however, the inherent issues of dendrite growth and huge volume fluctuations upon Li plating/stripping normally result in fast capacity fading and safety concerns. Functionalized Cu current collectors have so far exhibited significant regulatory effects on stabilizing Li metal anodes (LMAs), and hold a great practical potential owing to their easy fabrication, low-cost and good compatibility with the existing battery technology. In this review, a comprehensive overview of Cu-based current collectors, including planar modified Cu foil, 3D architectured Cu foil and nanostructured 3D Cu substrates, for Li metal batteries is provided. Particularly, the design principles and strategies of functionalized Cu current collectors associated with their functionalities in optimizing Li plating/stripping behaviors are discussed. Finally, the critical issues where there is incomplete understanding and the future research directions of Cu current collectors in practical LMAs are also prospected. This review may shed light on the critical understanding of current collector engineering for high-energy-density Li metal batteries.


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About this article

Present and future of functionalized Cu current collectors for stabilizing lithium metal anodes

Show Author's information Yuhang Liu1,§, Yifan Li1,§, Jinmeng Sun1, Zhuzhu Du1, Xiaoqi Hu1, Jingxuan Bi1, Chuntai Liu4, Wei Ai1( ), Qingyu Yan2,3( )
Frontiers Science Center for Flexible Electronics (FSCFE) & Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi'an 710072, China
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798 Singapore
Institute of Materials Research and Engineering, A*STAR, 138634 Singapore
Key Laboratory of Materials Processing and Mold Ministry of Education, Zhengzhou University, Zhengzhou 450002, China

§ Yuhang Liu and Yifan Li contributed equally to this work.

Abstract

Li metal has been recognized as the most promising anode materials for next-generation high-energy-density batteries, however, the inherent issues of dendrite growth and huge volume fluctuations upon Li plating/stripping normally result in fast capacity fading and safety concerns. Functionalized Cu current collectors have so far exhibited significant regulatory effects on stabilizing Li metal anodes (LMAs), and hold a great practical potential owing to their easy fabrication, low-cost and good compatibility with the existing battery technology. In this review, a comprehensive overview of Cu-based current collectors, including planar modified Cu foil, 3D architectured Cu foil and nanostructured 3D Cu substrates, for Li metal batteries is provided. Particularly, the design principles and strategies of functionalized Cu current collectors associated with their functionalities in optimizing Li plating/stripping behaviors are discussed. Finally, the critical issues where there is incomplete understanding and the future research directions of Cu current collectors in practical LMAs are also prospected. This review may shed light on the critical understanding of current collector engineering for high-energy-density Li metal batteries.

Keywords: functionalization, Li metal batteries, Cu current collectors, lithiophilic modification, Li plating/stripping

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Publication history
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Publication history

Received: 28 October 2022
Revised: 24 November 2022
Accepted: 27 November 2022
Published: 06 January 2023
Issue date: March 2023

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© The Author(s) 2023. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 22279104, 51902261 and 61935017), the National Key Research and Development Program of China (No. 2020YFA0709900), the Singapore Ministry of Education AcRF Tier 1: 2020-T1-001-031, RG4/20, the 111 project (D18023) from Zhengzhou University.

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