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Nano Research Energy 2023, 2: e9120046 https://doi.org/10.26599/NRE.2023.9120046
Review Article | Open Access | Issue | Published: 09 December 2022

Mechanism, quantitative characterization, and inhibition of corrosion in lithium batteries

Show Author's Information Yang-Yang Wang1,2,  Xue-Qiang Zhang1,2( ),  Ming-Yue Zhou3,  Jia-Qi Huang1,2( )
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
Beijing Key Laboratory of Green Chemical, Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
Keywords:
lithium batteries, corrosion inhibition, corrosion mechanism, quantitative method
Cite this article:
Wang Y-Y, Zhang X-Q, Zhou M-Y, et al. Mechanism, quantitative characterization, and inhibition of corrosion in lithium batteries. Nano Research Energy, 2023, 2: e9120046. https://doi.org/10.26599/NRE.2023.9120046
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Abstract Full text About this article

Rechargeable lithium batteries with long calendar life are pivotal in the pursuit of non-fossil and wireless society as energy storage devices. However, corrosion has severely plagued the calendar life of lithium batteries. The corrosion in batteries mainly occurs between electrode materials and electrolytes, which results in constant consumption of active materials and electrolytes and finally premature failure of batteries. Therefore, understanding the mechanism of corrosion and developing strategies to inhibit corrosion are imperative for lithium batteries with long calendar life. In this review, different types of corrosion in batteries are summarized and the corresponding corrosion mechanisms are firstly clarified. Secondly, quantitative studies of the loss of lithium in corrosion are reviewed for an in-depth understanding of the mechanism. Thirdly, the recent progress in inhibiting corrosion is demonstrated. Finally, perspectives to further investigate corrosion mechanism and inhibit corrosion are put forward to promote the development of stable lithium batteries.


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About this article

Mechanism, quantitative characterization, and inhibition of corrosion in lithium batteries

Show Author's information Yang-Yang Wang1,2, Xue-Qiang Zhang1,2( ), Ming-Yue Zhou3, Jia-Qi Huang1,2( )
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
Beijing Key Laboratory of Green Chemical, Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Abstract

Rechargeable lithium batteries with long calendar life are pivotal in the pursuit of non-fossil and wireless society as energy storage devices. However, corrosion has severely plagued the calendar life of lithium batteries. The corrosion in batteries mainly occurs between electrode materials and electrolytes, which results in constant consumption of active materials and electrolytes and finally premature failure of batteries. Therefore, understanding the mechanism of corrosion and developing strategies to inhibit corrosion are imperative for lithium batteries with long calendar life. In this review, different types of corrosion in batteries are summarized and the corresponding corrosion mechanisms are firstly clarified. Secondly, quantitative studies of the loss of lithium in corrosion are reviewed for an in-depth understanding of the mechanism. Thirdly, the recent progress in inhibiting corrosion is demonstrated. Finally, perspectives to further investigate corrosion mechanism and inhibit corrosion are put forward to promote the development of stable lithium batteries.

Keywords: lithium batteries, corrosion inhibition, corrosion mechanism, quantitative method

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Publication history

Received: 17 October 2022
Revised: 18 November 2022
Accepted: 21 November 2022
Published: 09 December 2022
Issue date: March 2023

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© The Author(s) 2023. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

This work was supported by the Beijing Natural Science Foundation (No. JQ20004), the National Key Research and Development Program (No. 2021YFB2400300), the National Natural Science Foundation of China (Nos. 22209010 and 22109007), China Postdoctoral Science Foundation (2021M700404), and Beijing Institute of Technology Research Fund Program for Young Scholars.

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