AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
PDF (21.9 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Review Article | Open Access

The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis

Xueping Zhang1,2, Wenli Wang1, Mei Hong3, Yamei Lin3,4, Guo-Ping Lu1( )
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
Institute of Intelligent Innovation, Henan Academy of Sciences, Zhengzhou 451162, China
International Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University, Nanjing 210037, China
School of Food Science and Pharmaceutical Engineering, Nanjing Normal University, Nanjing 210023, China
Show Author Information

Abstract

Polyolefins represent the most extensively manufactured category of plastics globally, whose ultra strong chemical stability makes their recycling challenging. Hydrogenolysis has emerged as a promising chemical recycling strategy for polyolefins, in which supports play an important but “silent” role. This review focuses on recent advances in polyolefin hydrogenolysis, with particular emphasis on how supports (acidity/basicity, reducibility, size/pore, optical activity) architecture dictate efficiency in the process. It also summarizes characterization methodologies for elucidating support effects. This review bridges the current research void in support-effect-mediated regulation of polyolefin hydrogenolysis, establishing rational design principles for carriers to boost the performance of metal-supported catalysts.

Graphical Abstract

This review summarizes the regulatory mechanisms of support effects on catalytic polyolefin hydrogenolysis activity and the corresponding characterization methods, establishing design principles for supports to enhance catalyst performance.

Keywords

polyolefinshydrogenolysissupport effectmetal-support interactionsC–C bond cleavage

References

【1】
【1】
 
 
Crossref Google Scholar
Nano Research
Volume 18 Issue 10,
October 2025
Article number: 94907962
DOI: 10.26599/NR.2025.94907962

{{item.num}}

Comments on this article

Go to comment

< Back to all reports

Review Status: {{reviewData.commendedNum}} Commended , {{reviewData.revisionRequiredNum}} Revision Required , {{reviewData.notCommendedNum}} Not Commended Under Peer Review

Review Comment

Cite this Report
Close
Close
Cite this article:
Zhang X, Wang W, Hong M, et al. The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis. Nano Research, 2025, 18(10): 94907962. https://doi.org/10.26599/NR.2025.94907962

1613

Views

210

Downloads

0

Crossref

0

Web of Science

0

Scopus

0

CSCD
Received: 23 June 2025
Revised: 29 July 2025
Accepted: 20 August 2025
Published: 30 September 2025
© The Author(s) 2025. Published by Tsinghua University Press.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, https://creativecommons.org/licenses/by/4.0/).