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Reversible Kirkendall effect enables the chemical transformation of reconfigurable nanocrystals

Li Zhai1,2Chao Wang1Hua Zhang1,2,3,4 ( )
Department of Chemistry, City University of Hong Kong, Hong Kong, China
Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM), City University of Hong Kong, Hong Kong, China
Hong Kong Institute for Clean Energy (HKICE), City University of Hong Kong, Kowloon, Hong Kong, China
Shenzhen Research Institute, City University of Hong Kong, Shenzhen 518057, China
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References

[1]

Smigelskas, A. D.; Kirkendall, E. O. Zinc diffusion in alpha brass. Trans. AIME 1947, 171, 130–142.

[2]

Tu, K. N.; Gösele, U. Hollow nanostructures based on the kirkendall effect: Design and stability considerations. Appl. Phys. Lett. 2005, 86, 093111.

[3]

Tianou, H.; Wang, W. C.; Yang, X. L.; Cao, Z. M.; Kuang, Q.; Wang, Z.; Shan, Z. W.; Jin, M. S.; Yin, Y. D. Inflating hollow nanocrystals through a repeated kirkendall cavitation process. Nat. Commun. 2017, 8, 1261.

[4]

Chen, Y.; Lai, Z.; Zhang, X.; Fan, Z.; He, Q.; Tan, C.; Zhang, H. Phase engineering of nanomaterials. Nat. Rev. Chem. 2020, 4, 243–256.

[5]

Xu, H. M.; Gu, C.; Wang, G.; Nan, P. F.; Zhang, J. D.; Shi, L.; Han, S. K.; Ge, B. H.; Wang, Y. G.; Li, J. et al. Kirkendall effect-driven reversible chemical transformation for reconfigurable nanocrystals. J. Am. Chem. Soc. 2024, 146, 30372–30379.

Nano Research
Article number: 94907184
Cite this article:
Zhai L, Wang C, Zhang H. Reversible Kirkendall effect enables the chemical transformation of reconfigurable nanocrystals. Nano Research, 2025, 18(2): 94907184. https://doi.org/10.26599/NR.2025.94907184

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Received: 07 December 2024
Accepted: 11 December 2024
Published: 15 January 2025
© The Author(s) 2025. Published by Tsinghua University Press.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, https://creativecommons.org/licenses/by/4.0/).

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