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Review Article | Open Access

Electrodeposited binder-free oxy-hydroxide nanostructures as promising electrocatalyst for hydrogen and oxygen evolution reactions

Danial Iravani1Ghasem Barati Darband2( )
Chemical Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad (FUM), 9177948944 Mashhad, Iran
Materials and Metallurgical Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad (FUM), 9177948944 Mashhad, Iran
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Abstract

In recent years, extensive research and development have been conducted on renewable energies to overcome the problems caused by fossil fuel consumption. In the meantime, the production of hydrogen energy through electrochemical water splitting (EWS) has been limited by various challenges, such as high required overpotential. Additionally, other methods of hydrogen production may lead to environmental problems, such as greenhouse gas emissions. Effective electrocatalysts can significantly mitigate the EWS challenges. Oxy-hydroxide compounds possess unique properties that make them effective electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Additionally, the utilization of the electrodeposition method, a binder-free technique, enables the production of electrodes exhibiting favorable electrocatalytic activity and stability. This review article provides an overview of the challenges associated with the EWS technique, highlighting the importance of transition metal oxy-hydroxide electrodes in facilitating the HER and OER reactions. Additionally, the paper evaluates the effectiveness of fabricated transition metal oxy-hydroxide electrodes through electrodeposition and suggests potential areas for future research on EWS.

Graphical Abstract

An introduction to electrochemical water splitting is followed by a comprehensive overview of the latest progress in transition metal-based oxy-hydroxide electrocatalysts synthesized with the electrodeposition technique. In addition, new approaches and innovative technologies are discussed for the preparation of highly efficient transition metal-based oxy-hydroxide electrocatalysts.

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Nano Research
Article number: 94907102

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Cite this article:
Iravani D, Darband GB. Electrodeposited binder-free oxy-hydroxide nanostructures as promising electrocatalyst for hydrogen and oxygen evolution reactions. Nano Research, 2025, 18(2): 94907102. https://doi.org/10.26599/NR.2025.94907102

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Received: 30 August 2024
Revised: 22 October 2024
Accepted: 30 October 2024
Published: 31 December 2024
© The Author(s) 2025. Published by Tsinghua University Press.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, https://creativecommons.org/licenses/by/4.0/).