AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
MXene-based absorbers have shown promising application prospects because of their sophisticated structural design and clever material composites. However, the intrinsic MXene materials themselves have not achieved significant breakthroughs in microwave absorption (MA) performance. Therefore, the development of novel and efficient pure MXene absorbing materials is imperative to address inherent mismatches in electromagnetic parameters, highlighting the urgent need in this area. Here, a straightforward strategy involving etching time modulation is proposed to customize the electromagnetic wave (EMW) absorption properties of delaminated Mo2CTx MXene. The impact of varying etching degrees on the EMW absorption capabilities of Mo2CTx MXenes was systematically investigated through controlled etching durations of Mo2Ga2C MAX phase. Among them, the sample etched for 12 h achieved an effective absorption bandwidth (EAB) of 4.4 GHz at an ultrathin thickness of 1.3 mm, and the strongest reflection loss (RL) value was as high as −60.7 dB when the sample etching time was increased to 24 h. The improvement in absorbing performance was attributed to the dielectric loss and polarization process induced by terminal functional groups and surface-rich defects, which optimized impedance matching. This work establishes that intrinsic Mo2CTx MXene materials with superior absorbing properties outperform traditional pure MXenes, providing a strong basis for advancing Mo-based MXene absorptive materials.
Zeng XJ, Jiang X, Ning Y, et al. Constructing built-in electric fields with semiconductor junctions and Schottky junctions based on Mo–MXene/Mo–metal sulfides for electromagnetic response. Nano-Micro Lett 2024, 16: 213.
Pang HF, Duan YP, Huang LX, et al. Research advances in composition, structure and mechanisms of microwave absorbing materials. Compos Part B Eng 2021, 224: 109173.
Wang Y, Gao X, Fu YQ, et al. Enhanced microwave absorption performances of polyaniline/graphene aerogel by covalent bonding. Compos Part B Eng 2019, 169: 221–228.
Song CQ, Yin XW, Han MK, et al. Three-dimensional reduced graphene oxide foam modified with ZnO nanowires for enhanced microwave absorption properties. Carbon 2017, 116: 50–58.
Jiang JL, Zhao WC, Zhao L. Ultrarapid gelation of porous Ti3C2T x MXene monoliths induced by ionic liquids. Nano Lett 2024, 24: 3196–3203.
Zhu YC, Rajouâ K, Le Vot S, et al. Modifications of MXene layers for supercapacitors. Nano Energy 2020, 73: 104734.
Liang CB, Qiu H, Song P, et al. Ultra-light MXene aerogel/wood-derived porous carbon composites with wall-like “mortar/brick” structures for electromagnetic interference shielding. Sci Bull 2020, 65: 616–622.
Fan JC, Yang RS, Du YQ, et al. A triboelectric nanogenerator based on MXene/TPU composite films with excellent stretchability for self-powered flexible sensing. Nano Energy 2024, 129: 109999.
Guo YT, Zhang X, Jin S, et al. Synthesis of Mo2C MXene with high electrochemical performance by alkali hydrothermal etching. J Adv Ceram 2023, 12: 1889–1901.
Qiao LJ, Bi JQ, Liang GD, et al. Synthesis of high-entropy MXenes with high-efficiency electromagnetic wave absorption. J Adv Ceram 2023, 12: 1902–1918.
Karataş Y, Çetin T, Akinay Y, et al. Synthesis and characterization of Pd doped MXene for hydrogen production from the hydrolysis of methylamine borane: Effect of cryogenic treatment. J Energy Inst 2023, 109: 101310.
Ulas B, Çetin T, Kaya Ş, et al. Novel Ti3C2X2 MXene supported BaMnO3 nanoparticles as hydrazine electrooxidation catalysts. Int J Hydrogen Energ 2024, 58: 726–736.
Zhang X, Zhang ZH, Zhou Z. MXene-based materials for electrochemical energy storage. J Energy Chem 2018, 27: 73–85.
Cui GZ, Zheng X, Lv XL, et al. Synthesis and microwave absorption of Ti3C2T x MXene with diverse reactant concentration, reaction time, and reaction temperature. Ceram Int 2019, 45: 23600–23610.
Du YQ, Yan ZK, You WB, et al. Balancing MXene surface termination and interlayer spacing enables superior microwave absorption. Adv Funct Mater 2023, 33: 2301449.
Liu Y, Zhao YB, Ma CT, et al. Ultralow-content Co decoration on Ti3C2T x MXene induced electromagnetic characteristic modulation for efficient microwave absorption. Ceram Int 2024, 50: 24406–24416.
Li N, Xie X, Lu HX, et al. Novel two-dimensional Ti3C2T x /Ni-spheres hybrids with enhanced microwave absorption properties. Ceram Int 2019, 45: 22880–22888.
Zhou CL, Wang XX, Luo H, et al. Interfacial design of sandwich-like CoFe@Ti3C2T x composites as high efficient microwave absorption materials. Appl Surf Sci 2019, 494: 540–550.
Kong L, Qi J, Li MH, et al. Electromagnetic wave absorption properties of Ti3C2T x nanosheets modified with in situ growth carbon nanotubes. Carbon 2021, 183: 322–331.
Wang Y, Dou Q, Jiang W, et al. Ti3C2T x MXene beaded SiC nanowires for efficient microwave absorption. ACS Appl Nano Mater 2022, 5: 9209–9222.
Li X, Wen CY, Yang LT, et al. Enhanced visualizing charge distribution of 2D/2D MXene/MoS2 heterostructure for excellent microwave absorption performance. J Alloys Compd 2021, 869: 159365.
Zhang HY, Ji H, Dai GL, et al. Nanoarchitectonics of integrated impedance gradient MXene/PPy/polyester composite fabric for enhanced microwave absorption performances. Compos Part A Appl S 2022, 163: 107163.
Han MK, Shuck CE, Singh A, et al. Efficient microwave absorption with V n +1C n T x MXenes. Cell Rep Phys Sci 2022, 3: 101073.
Miao BJ, Cao YG, Zhu QS, et al. Scalable synthesis of 2D Ti2CT x MXene and molybdenum disulfide composites with excellent microwave absorbing performance. Adv Compos Hybrid Mater 2023, 6: 61.
Song SW, Liu JQ, Zhou CL, et al. Nb2O5/Nb2CT x composites with different morphologies through oxidation of Nb2CT x MXene for high-performance microwave absorption. J Alloys Compd 2020, 843: 155713.
Kumaravel V, Rhatigan S, Mathew S, et al. Mo doped TiO2: Impact on oxygen vacancies, anatase phase stability and photocatalytic activity. J Phys Mater 2020, 3: 025008.
He WY, Zheng XJ, Peng JF, et al. Mo-dopant-strengthened basal-plane activity in VS2 for accelerating hydrogen evolution reaction. Chem Eng J 2020, 396: 125227.
Hu FY, Wang XH, Niu HH, et al. Synthesis and electromagnetic wave absorption of novel Mo2TiC2T x MXene with diverse etching methods. J Mater Sci 2022, 57: 7849–7862.
Yang K, Cui YH, Wan LY, et al. Preparation of three-dimensional Mo2C/NC@MXene and its efficient electromagnetic absorption properties. ACS Appl Mater Inter 2022, 14: 7109–7120.
Guo TJ, Chang SQ, Akinay Y. Synthesis of PPy@Ba0.5Sr0.5Fe12O19/CNFs by reverse in situ polymerization method for microwave absorption applications. Synthetic Met 2020, 266: 116387.
Jin S, Su TC, Hu QK, et al. Thermal conductivity and electrical transport properties of double-A-layer MAX phase Mo2Ga2C. Mater Res Lett 2020, 8: 158–164.
Min J, Wang KY, Liu J, et al. Facile synthesis of uniform MoO2/Mo2CT x heteromicrospheres as high-performance anode materials for lithium-ion batteries. J Power Sources 2017, 363: 392–403.
Kim H, Anasori B, Gogotsi Y, et al. Thermoelectric properties of two-dimensional molybdenum-based MXenes. Chem Mater 2017, 29: 6472–6479.
Gong CC, Ding JW, Wang CX, et al. Defect-induced dipole polarization engineering of electromagnetic wave absorbers: Insights and perspectives. Compos Part B Eng 2023, 252: 110479.
Guo YT, Jin S, Wang LB, et al. Synthesis of two-dimensional carbide Mo2CT x MXene by hydrothermal etching with fluorides and its thermal stability. Ceram Int 2020, 46: 19550–19556.
Jabbarvand Behrouz S, Khataee A, Vatanpour V, et al. Surface bioengineering of Mo2Ga2C MAX phase to develop blended loose nanofiltration membranes for textile wastewater treatment. ACS Appl Mater Inter 2024, 16: 10508–10521.
Xu HJ, Dong HL, Liu XT, et al. High-temperature oxidized Mo2CT x MXene for a high-performance supercapacitor. ACS Appl Mater Inter 2023, 15: 53549–53557.
Surdu-Bob CC, Saied SO, Sullivan JL. An X-ray photoelectron spectroscopy study of the oxides of GaAs. Appl Surf Sci 2001, 183: 126–136.
Lykiema J, Sing KSW, Haber J, et al. Reporting physisorption data for gas/solid systems. Pure & App Chem 1984, 4: 603–619.
Zeng XJ, Jiang X, Ning Y, et al. Construction of dual heterogeneous interface between zigzag-like Mo–MXene nanofibers and small CoNi@NC nanoparticles for electromagnetic wave absorption. J Adv Ceram 2023, 12: 1562–1576.
Wang L, Lu JT, Zhang JL, et al. Facile preparation and high microwave absorption of flower-like carbon nanosheet aggregations embedded with ultrafine Mo2C. J Colloid Interf Sci 2023, 641: 729–736.
Wen CY, Li X, Zhang RX, et al. High-density anisotropy magnetism enhanced microwave absorption performance in Ti3C2T x MXene@Ni microspheres. ACS Nano 2022, 16: 1150–1159.
Du H, Zhang QP, Zhao B, et al. Novel hierarchical structure of MoS2/TiO2/Ti3C2T x composites for dramatically enhanced electromagnetic absorbing properties. J Adv Ceram 2021, 10: 1042–1051.
Sun MX, Wang DR, Xiong ZM, et al. Multi-dimensional Ni@C–CoNi composites with strong magnetic interaction toward superior microwave absorption. J Mater Sci Technol 2022, 130: 176–183.
Huang WH, Zhang XX, Zhao YN, et al. Hollow N-doped carbon polyhedra embedded Co and Mo2C nanoparticles for high-efficiency and wideband microwave absorption. Carbon 2020, 167: 19–30.
Qin M, Zhang LM, Wu HJ. Dielectric loss mechanism in electromagnetic wave absorbing materials. Adv Sci 2022, 9: 2105553.
Wang G, Li CF, Estevez D, et al. Boosting interfacial polarization through heterointerface engineering in MXene/graphene intercalated-based microspheres for electromagnetic wave absorption. Nano-Micro Lett 2023, 15: 152.
Wu CW, Zhang F, Zhi Q, et al. From binary to ternary and back to binary: Transition of electromagnetic wave shielding to absorption among MAB phase Ni3ZnB2 and corresponding binary borides Ni n +1 B n ( n = 1, 3). J Adv Ceram 2023, 12: 2101–2111.
Meng XW, Qiao J, Yang YF, et al. Three-dimensional porous manganese oxide/nickel/carbon microspheres as high-performance electromagnetic wave absorbers with superb photothermal property. J Colloid Interf Sci 2023, 629: 884–894.
Wang L, Cai ZX, Su L, et al. Bifunctional SiC/Si3N4 aerogel for highly efficient electromagnetic wave absorption and thermal insulation. J Adv Ceram 2023, 12: 309–320.
Liu PB, Zheng SY, He ZZ, et al. Optimizing integrated-loss capacities via asymmetric electronic environments for highly efficient electromagnetic wave absorption. Small 2024, 20: 2403903.
Shi YX, Liang BQ, Gao H, et al. Research progress on spherical carbon-based electromagnetic wave absorbing composites. Carbon 2024, 227: 119244.
Gou JL, Chang YK, Liu S, et al. Solid solution strategy modulated defects engineering of (Cr1− x V x )2AlC MAX phase toward superior electromagnetic wave absorption. Rare Metals 2024, 43: 3205–3219.
Liu PB, Gao S, Wang Y, et al. Metal-organic polymer coordination materials derived Co/N-doped porous carbon composites for frequency-selective microwave absorption. Compos Part B Eng 2020, 202: 108406.
Xu HL, Yin XW, Li XL, et al. Thermal stability and dielectric properties of 2D Ti2C MXenes via annealing under a gas mixture of Ar and H2 atmosphere. Funct Compos Struct 2019, 1: 015002.
Ning MQ, Lu MM, Li JB, et al. Two-dimensional nanosheets of MoS2: A promising material with high dielectric properties and microwave absorption performance. Nanoscale 2015, 7: 15734–15740.
Jin ZY, Fang YF, Wang XX, et al. Ultra-efficient electromagnetic wave absorption with ethanol-thermally treated two-dimensional Nb2CT x nanosheets. J Colloid Interf Sci 2019, 537: 306–315.
Fan BB, Li N, Dai BZ, et al. Investigation of adjacent spacing dependent microwave absorption properties of lamellar structural Ti3C2T x MXenes. Adv Powder Technol 2020, 31: 808–815.
Zhu LL, Wu WW, Chen JJ, et al. High-performance electromagnetic wave absorption by two-dimensional mesoporous monolayer Ti3C2T x MXene. Chem Eng J 2024, 488: 150649.
528
Views
98
Downloads
0
Crossref
0
Web of Science
0
Scopus
0
CSCD
Altmetrics
This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).
京公网安备11010802044758号