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Research Article | Open Access

Simultaneously enhanced energy storage performance and luminance resistance in (K0.5Na0.5)NbO3-based ceramics via synergistic optimization strategy

Yu Huan1Diyu Gui2Changxiao Li1Tao Wei1( )Lingzhi Wu1Xinjian Wang3Xiaozhi Wang3Zhenxiang Cheng4( )
School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
Yangtze Delta Region Transformation Center for Advanced Technological Achievements, Suzhou 215000, China
Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University, Xi’an 710032, China
Institute for Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Innovation Campus, North Wollongong 2500, Australia
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Abstract

The rapidly advancing energy storage performance of dielectric ceramics capacitors has garnered significant interest for applications in fast charge/discharge and high-power electronic techniques. Exploring the exceptional electrical properties in harsh environments can further promote their practical applications. Defect carriers can be excited under luminance irradiation, thereby leading to degradation of energy storage performance. Herein, a synergic optimization strategy is proposed to enhance energy storage properties and luminance resistance of (K0.5Na0.5)NbO3-base (KNN) ceramics. First, the introduction of Bi(Zn0.5Ti0.5)O3 solid solution and La3+ ions disrupts the long-range polar orders and enhances super paraelectric relaxation characteristics. Additionally, doping La3+ ions can increase the band gap and reduce oxygen vacancy concentration, resulting in excellent luminance resistance. Finally, the viscous polymer process is employed to suppress the grain growth and promote chemical homogeneity. As a result, ultrahigh recoverable energy storage density (Wrec) of 8.11 J/cm3 and high efficiency (η) of 80.98% are achieved under an electric field of 568 kV/cm. Moreover, the variations in Wrec and η are only 12.45% and 1.75%, respectively, under 500 W xenon lamp irradiation compared to the performance under a dark environment. These findings hold great potential in facilitating the practical application of dielectric ceramic capacitors in luminance irradiation environments.

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Journal of Advanced Ceramics
Pages 34-43
Cite this article:
Huan Y, Gui D, Li C, et al. Simultaneously enhanced energy storage performance and luminance resistance in (K0.5Na0.5)NbO3-based ceramics via synergistic optimization strategy. Journal of Advanced Ceramics, 2024, 13(1): 34-43. https://doi.org/10.26599/JAC.2024.9220833

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Received: 12 September 2023
Revised: 06 November 2023
Accepted: 26 November 2023
Published: 18 January 2024
© The Author(s) 2024.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).

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