AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (2.3 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Synergetic effect of lattice distortion and oxygen vacancies on high-rate lithium-ion storage in high-entropy perovskite oxides

Yanggang JiaaShijie ChenaXia ShaoaJie ChenaDao-Lai FangaSaisai LiaAiqin Maoa,b( )Canhua Lic( )
School of Materials Science and Engineering, Anhui University of Technology, Ma’anshan 243032, China
Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Ministry of Education, Anhui University of Technology, Ma’anshan 243002, China
School of Metallurgical Engineering, Anhui University of Technology, Ma’anshan 243032, China
Show Author Information

Graphical Abstract

Abstract

High-entropy oxides (HEOs) have gained great attention as an emerging kind of high-performance anode materials for lithium-ion batteries (LIBs) due to the entropy stabilization and multi-principal synergistic effect. Herein, the porous perovskite-type RE(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O3 (RE (= La, Sm, and Gd) is the abbreviation of rare earth) HEOs were successfully synthesized by a solution combustion synthesis (SCS) method. Owing to the synergistic effect of lattice distortion and oxygen vacancies (OV), the Gd(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O3 electrode exhibits superior high-rate lithium-ion storage performance and excellent cycling stability. A reversible capacity of 403 mAh·g–1 at a current rate of 0.2 A·g–1 after 500 cycles and a superior high-rate capacity of 394 mAh·g−1 even at 1.0 A·g–1 after 500 cycles are achieved. Meanwhile, the Gd(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O3 electrode also exhibits a pronounced pseudo-capacitive behavior, contributing to an additional capacity. By adjusting and balancing the lattice distortion and oxygen vacancies of the electrode materials, the lithium-ion storage performance can be further regulated.

References

[1]
Sarkar A, Velasco L, Wang D, et al. High entropy oxides for reversible energy storage. Nat Commun 2018, 9: 3400.
[2]
Xu YS, Xu X, Bi L. A high-entropy spinel ceramic oxide as the cathode for proton-conducting solid oxide fuel cells. J Adv Ceram 2022, 11: 794–804.
[3]
Xiang HM, Xing Y, Dai FZ, et al. High-entropy ceramics: Present status, challenges, and a look forward. J Adv Ceram 2021, 10: 385–441.
[4]
Zhao J, Yang X, Huang Y, et al. Entropy stabilization effect and oxygen vacancies enabling spinel oxide highly reversible lithium-ion storage. ACS Appl Mater Interfaces 2021, 13: 58674–58681.
[5]
Yuan K, Tu TZ, Shen C, et al. Self-ball milling strategy to construct high-entropy oxide coated LiNi0.8Co0.1Mn0.1O2 with enhanced electrochemical performance. J Adv Ceram 2022, 11: 882–892.
[6]
Yan SX, Luo SH, Yang L, et al. Novel P2-type layered medium-entropy ceramics oxide as cathode material for sodium-ion batteries. J Adv Ceram 2022, 11: 158–171.
[7]
Ning YT, Pu YP, Wu CH, et al. Enhanced capacitive energy storage and dielectric temperature stability of A-site disordered high-entropy perovskite oxides. J Mater Sci Technol 2023, 145: 66–73.
[8]
Wang YH, Liu JP, Song YF, et al. High-entropy perovskites for energy conversion and storage: Design, synthesis, and potential applications. Small Methods 2023, .
[9]
Bérardan D, Franger S, Meena AK, et al. Room temperature lithium superionic conductivity in high entropy oxides. J Mater Chem A 2016, 4: 9536–9541.
[10]
Wang QS, Sarkar A, Li ZY, et al. High entropy oxides as anode material for Li-ion battery applications: A practical approach. Electrochem Commun 2019, 100: 121–125.
[11]
Qiu N, Chen H, Yang ZM, et al. A high entropy oxide (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O) with superior lithium storage performance. J Alloys Compd 2019, 777: 767–774.
[12]
Chen H, Qiu N, Wu BZ, et al. Tunable pseudocapacitive contribution by dimension control in nanocrystalline-constructed (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O solid solutions to achieve superior lithium-storage properties. RSC Adv 2019, 9: 28908–28915.
[13]
Wang D, Jiang SD, Duan CQ, et al. Spinel-structured high entropy oxide (FeCoNiCrMn)3O4 as anode towards superior lithium storage performance. J Alloys Compd 2020, 844: 156158.
[14]
Chen H, Qiu N, Wu BZ, et al. A new spinel high-entropy oxide (Mg0.2Ti0.2Zn0.2Cu0.2Fe0.2)3O4 with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries. RSC Adv 2020, 10: 9736–9744.
[15]
Sun Z, Zhao YJ, Sun C, et al. High entropy spinel-structure oxide for electrochemical application. Chem Eng J 2022, 431: 133448.
[16]
Xiao B, Wu G, Wang TD, et al. High-entropy oxides as advanced anode materials for long-life lithium-ion batteries. Nano Energy 2022, 95: 106962.
[17]
Lun ZY, Ouyang B, Kwon DH, et al. Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries. Nat Mater 2021, 20: 214–221.
[18]
Yang XB, Wang HQ, Song YY, et al. Low-temperature synthesis of a porous high-entropy transition-metal oxide as an anode for high-performance lithium-ion batteries. ACS Appl Mater Interfaces 2022, 14: 26873–26881.
[19]
Luo XF, Patra J, Chuang WT, et al. Charge–discharge mechanism of high-entropy Co-free spinel oxide toward Li+ storage examined using operando quick-scanning X-ray absorption spectroscopy. Adv Sci 2022, 9: 2201219.
[20]
Ma JX, Chen KP, Li CW, et al. High-entropy stoichiometric perovskite oxides based on valence combinations. Ceram Int 2021, 47: 24348–24352.
[21]
Nguyen AT, Phung VD, Mittova VO, et al. Fabricating nanostructured HoFeO3 perovskite for lithium-ion battery anodes via co-precipitation. Scripta Mater 2022, 207: 114259.
[22]
Hu QL, Yue B, Shao HY, et al. Facile syntheses of perovskite type LaMO3 (M = Fe, Co, Ni) nanofibers for high performance supercapacitor electrodes and lithium-ion battery anodes. J Alloys Compd 2021, 852: 157002.
[23]
Yan JH, Wang D, Zhang XY, et al. A high-entropy perovskite titanate lithium-ion battery anode. J Mater Sci 2020, 55: 6942–6951.
[24]
Li L, Xie ZJ, Jiang GX, et al. Efficient laser-induced construction of oxygen-vacancy abundant nano-ZnCo2O4/ porous reduced graphene oxide hybrids toward exceptional capacitive lithium storage. Small 2020, 16: 2001526.
[25]
Mao AQ, Xiang HZ, Zhang ZG, et al. A new class of spinel high-entropy oxides with controllable magnetic properties. J Magn Magn Mater 2020, 497: 165884.
[26]
Mao AQ, Xie HX, Xiang HZ,et al. A novel six-component spinel-structure high-entropy oxide with ferrimagnetic property. J Magn Magn Mater 2020, 503: 166594.
[27]
Xiang HZ, Xie HX, Chen YX, et al. Porous spinel-type (Al0.2CoCrFeMnNi)0.58O4−δ high-entropy oxide as a novel high-performance anode material for lithium-ion batteries. J Mater Sci 2021, 56: 8127–8142.
[28]
Xiang HZ, Xie HX, Li WC, et al. Synthesis and electrochemical performance of spinel-type high-entropy oxides. Chem J Chinese Universities 2020, 41: 1801–1809. (in Chinese)
[29]
Sarkar A, Djenadic R, Wang D, et al. Rare earth and transition metal based entropy stabilised perovskite type oxides. J Eur Ceram Soc 2018, 38: 2318–2327.
[30]
Witte R, Sarkar A, Kruk R, et al. High-entropy oxides: An emerging prospect for magnetic rare-earth transition metal perovskites. Phys Rev Mater 2019, 3: 034406.
[31]
Elsiddig ZA, Xu H, Wang D, et al. Modulating Mn4+ ions and oxygen vacancies in nonstoichiometric LaMnO3 perovskite by a facile sol–gel method as high-performance supercapacitor electrodes. Electrochim Acta 2017, 253: 422–429.
[32]
Han XY, Cui YP, Liu HW. Ce-doped Mn3O4 as high-performance anode material for lithium ion batteries. J Alloys Compd 2020, 814: 152348.
[33]
Wang M, Chen L, Liu M, et al. Enhanced electrochemical performance of La-doped Li-rich layered cathode material. J Alloys Compd 2020, 848: 156620.
[34]
Patra J, Nguyen TX, Tsai CC, et al. Effects of elemental modulation on phase purity and electrochemical properties of Co-free high-entropy spinel oxide anodes for lithium-ion batteries. Adv Funct Mater 2022, 32: 2110992.
[35]
Li S, Peng ZJ, Fu XL. Zn0.5Co0.5Mn0.5Fe0.5Al0.5Mg0.5O4 high-entropy oxide with high capacity and ultra-long life for Li-ion battery anodes. J Adv Ceram 2023, 12: 59–71.
[36]
Li W, Liu J, Zhao DY. Mesoporous materials for energy conversion and storage devices. Nat Rev Mater 2016, 1: 16023.
[37]
Ashok A, Kumar A, Bhosale RR, et al. Combustion synthesis of bifunctional LaMO3 (M = Cr, Mn, Fe, Co, Ni) perovskites for oxygen reduction and oxygen evolution reaction in alkaline media. J Electroanal Chem 2018, 809: 22–30.
[38]
Khort A, Podbolotov K, Serrano-García R, et al. One-step solution combustion synthesis of cobalt nanopowder in air atmosphere: The fuel effect. Inorg Chem 2018, 57: 1464–1473.
[39]
Biesinger MC, Payne BP, Grosvenor AP, et al. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl Surf Sci 2011, 257: 2717–2730.
[40]
Guo M, Liu YF, Zhang FN, et al. Inactive Al3+-doped La(CoCrFeMnNiAlx)1/(5+x)O3 high-entropy perovskite oxides as high performance supercapacitor electrodes. J Adv Ceram 2022, 11: 742–753.
[41]
Sanchez JS, Pendashteh A, Palma J, et al. Porous NiCoMn ternary metal oxide/graphene nanocomposites for high performance hybrid energy storage devices. Electrochim Acta 2018, 279: 44–56.
[42]
Zhu YM, Zhang L, Zhao BT, et al. Improving the activity for oxygen evolution reaction by tailoring oxygen defects in double perovskite oxides. Adv Funct Mater 2019, 29: 1901783.
[43]
Zhang YY, Chen P, Wang QY, et al. High-capacity and kinetically accelerated lithium storage in MoO3 enabled by oxygen vacancies and heterostructure. Adv Energy Mater 2021, 11: 2101712.
[44]
Wang DR, Li HY, Li CJ, et al. Oxygen-deficient and orderly mesoporous cobalt oxide nanospheres for superior lithium storage. J Alloys Compd 2021, 887: 161339.
[45]
Cui Y, Xiao KF, Bedford NM, et al. Refilling nitrogen to oxygen vacancies in ultrafine tungsten oxide clusters for superior lithium storage. Adv Energy Mater 2019, 9: 1902148.
[46]
Kim HS, Cook JB, Lin H, et al. Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x. Nat Mater 2017, 16: 454–460.
[47]
Cai YX, Ku L, Wang LS, et al. Engineering oxygen vacancies in hierarchically Li-rich layered oxide porous microspheres for high-rate lithium ion battery cathode. Sci China Mater 2019, 62: 1374–1384.
[48]
Jia DD, Chen XQ, Tan H, et al. Boosting electrochemistry of manganese oxide nanosheets by Ostwald ripening during reduction for fiber electrochemical energy storage device. ACS Appl Mater Interfaces 2018, 10: 30388–30399.
[49]
Tang ZK, Xue YF, Teobaldi G, et al. The oxygen vacancy in Li-ion battery cathode materials. Nanoscale Horiz 2020, 5: 1453–1466.
[50]
Zhang N, Liu EQ, Chen HW, et al. High-performance of LaCoO3/Co3O4 nanocrystal as anode for lithium-ion batteries. Colloid Surface A 2021, 628: 127265.
[51]
Wang SY, Chen TY, Kuo CH, et al. Operando synchrotron transmission X-ray microscopy study on (Mg,Co,Ni,Cu,Zn)O high-entropy oxide anodes for lithium-ion batteries. Mater Chem Phys 2021, 274: 125105.
[52]
Cao KZ, Jin T, Yang L, et al. Recent progress in conversion reaction metal oxide anodes for Li-ion batteries. Mater Chem Front 2017, 1: 2213–2242.
[53]
Zhang QY, Zhang CL, Li B, et al. Preparation and electrochemical properties of Ca-doped Li4Ti5O12 as anode materials in lithium-ion battery. Electrochim Acta 2013, 98: 146–152.
[54]
Sarkar A, Wang QS, Schiele A, et al. High-entropy oxides: Fundamental aspects and electrochemical properties. Adv Mater 2019, 31: 1806236.
[55]
Kong YZ, Yang ZR. Synthesis, structure and electrochemical properties of Al doped high entropy perovskite Lix(LiLaCaSrBa)Ti1−xAlxO3. Ceram Int 2022, 48: 5035–5039.
[56]
Jia YG, Shao X, Chen J, et al. Preparation and lithium storage performance of pseudocapacitance-controlled chalcogenide high-entropy oxide La(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O3 anode materials. Chem J Chinese Universities 2022, 43: 20220157. (in Chinese)
[57]
Ogunniran KO, Murugadoss G, Thangamuthu R, et al. Evaluation of nanostructured Nd0.7Co0.3FeO3 perovskite obtained via hydrothermal method as anode material for Li-ion battery. Mater Chem Phys 2020, 248: 122944.
[58]
Chang LM, Li JH, Le ZY, et al. Perovskite-type CaMnO3 anode material for highly efficient and stable lithium ion storage. J Colloid Interf Sci 2021, 584: 698–705.
[59]
Wang K, Hua WB, Huang XH, et al. Synergy of cations in high entropy oxide lithium ion battery anode. Nat Commun 2023, 14: 1487.
[60]
Lu CH, Lin SW. Influence of the particle size on the electrochemical properties of lithium manganese oxide. J Power Sources 2001, 97–98: 458–460.
[61]
Maleski K, Ren CE, Zhao MQ, et al. Size-dependent physical and electrochemical properties of two-dimensional MXene flakes. ACS Appl Mater Interfaces 2018, 10: 24491–24498.
[62]
Ghigna P, Airoldi L, Fracchia M, et al. Lithiation mechanism in high-entropy oxides as anode materials for Li-ion batteries: An operando XAS study. ACS Appl Mater Interfaces 2020, 12: 50344–50354.
[63]
Zhong Y, Xia XH, Shi F, et al. Transition metal carbides and nitrides in energy storage and conversion. Adv Sci 2016, 3: 1500286.
Journal of Advanced Ceramics
Pages 1214-1227
Cite this article:
Jia Y, Chen S, Shao X, et al. Synergetic effect of lattice distortion and oxygen vacancies on high-rate lithium-ion storage in high-entropy perovskite oxides. Journal of Advanced Ceramics, 2023, 12(6): 1214-1227. https://doi.org/10.26599/JAC.2023.9220751

2336

Views

533

Downloads

19

Crossref

17

Web of Science

5

Scopus

0

CSCD

Altmetrics

Received: 02 March 2023
Revised: 08 April 2023
Accepted: 11 April 2023
Published: 05 June 2023
© The Author(s) 2023.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Return