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For noncontact optical thermometry, in contrast with fluorescence intensity ratio (FIR) technology, excitation intensity ratio (EIR) technology has been seriously limited due to low sensitivity. Moreover, by exploring all possible temperature-dependent response, developing multimode optical thermometry is of great importance. In this work, a new Na2Y2TeB2O10 (NYTB):Tb3+ phosphor is obtained by a solid-state reaction. Based on FIR and EIR models of Tb3+, thermometric properties are studied thoroughly. Excellent relative and absolute sensitivity (SR and SA) are acquired due to the significant difference in emission/excitation lines in response to temperature. Meanwhile, Tb3+ content-dependent luminescence quenching mechanism is discussed. This study shows a feasible route for exploiting well-performing FIR-/EIR-based thermometric materials.


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Thermometric properties of Na2Y2TeB2O10:Tb3+ green phosphor based on fluorescence/excitation intensity ratio

Show Author's information Yuefei XiangLin YangCanyuan LiaoXianfeng XiangXiangkai TangHanlin TangJing Zhu( )
Key Laboratory of LCR Materials and Devices of Yunnan Province, Yunnan Key Laboratory of Carbon Neutrality and Green Low-carbon Technologies, School of Materials and Energy, Yunnan University, Kunming 650091, China

† Yuefei Xiang and Lin Yang contributed equally to this work.

Abstract

For noncontact optical thermometry, in contrast with fluorescence intensity ratio (FIR) technology, excitation intensity ratio (EIR) technology has been seriously limited due to low sensitivity. Moreover, by exploring all possible temperature-dependent response, developing multimode optical thermometry is of great importance. In this work, a new Na2Y2TeB2O10 (NYTB):Tb3+ phosphor is obtained by a solid-state reaction. Based on FIR and EIR models of Tb3+, thermometric properties are studied thoroughly. Excellent relative and absolute sensitivity (SR and SA) are acquired due to the significant difference in emission/excitation lines in response to temperature. Meanwhile, Tb3+ content-dependent luminescence quenching mechanism is discussed. This study shows a feasible route for exploiting well-performing FIR-/EIR-based thermometric materials.

Keywords: photoluminescence (PL), Tb3+ ion, thermometric properties, Na2Y2TeB2O10 (NYTB)

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Publication history

Received: 27 October 2022
Revised: 12 January 2023
Accepted: 27 January 2023
Published: 10 March 2023
Issue date: April 2023

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© The Author(s) 2023.

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 22165031), National Undergraduate Innovation and Entrepreneurship Foundation (Nos. 202210673034 and 202210673052), and Program for Excellent Young Talents, Yunnan University. We thank Advanced Analysis and Measurement Center of Yunnan University for the sample testing service.

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