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Multifunctional, wearable, and durable textiles integrated with smart electronics have attracted tremendous attention. However, it remains a great challenge to balance new functionalities with high-temperature stability. Herein, textile-based pressure sensors with excellent electromagnetic interference (EMI) shielding, Joule heating, and high-temperature resistance were fabricated by constructing graphene/SiC (G/SiC) heterostructures on carbon cloth via laser chemical vapor deposition (LCVD). The resultant textiles exhibited excellent EMI efficiency of 74.2 dB with a thickness of 0.45 mm, Joule heating performance within a low working voltage (V) range of 1–3 V, and fast response time within 20 s. These properties arose from multiple reflections, interfacial polarization, and high conductivity due to the numerous amounts of nanoscale G/SiC heterostructures. More importantly, G/SiC/carbon fibers (CFs) demonstrated well high-temperature resistance with a heat resistance index (THRI) of 380.2 ℃ owing to the protection of a coating layer on the CFs upon oxidation. Meanwhile, the G/SiC/CFs presented good pressure-sensing performance with high sensitivity (S) of 52.93 kPa−1, fast response time of 85 ms, and a wide pressure range of up to 186 kPa. These features imply the potential of the G/SiC/CFs as efficient EMI shielding, electrical heater, and piezoresistive sensor textiles.


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Graphene/SiC-coated textiles with excellent electromagnetic interference shielding, Joule heating, high-temperature resistance, and pressure-sensing performances

Show Author's information Chongjie Wanga,Qingfang Xub,g,Jinrong HuaPengjian Lua,cHan WuaBingjian Guoa,eRong Tub,d,fKai LiuaMeijun YangbSong Zhangb( )Bao-Wen LiaChuanbin WangbLianmeng Zhangb,d
School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
Wuhan Tuocai Technology Co., Ltd., Ezhou 436032, China
Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Chaozhou 521000, China
Zhejiang MTCN Technology Co., Ltd., Huzhou 311103, China
Wuhan University of Technology Advanced Engineering Technology Research Institute of Zhongshan City, Zhongshan 528400, China
School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China

† Chongjie Wang and Qingfang Xu contributed equally to this work.

Abstract

Multifunctional, wearable, and durable textiles integrated with smart electronics have attracted tremendous attention. However, it remains a great challenge to balance new functionalities with high-temperature stability. Herein, textile-based pressure sensors with excellent electromagnetic interference (EMI) shielding, Joule heating, and high-temperature resistance were fabricated by constructing graphene/SiC (G/SiC) heterostructures on carbon cloth via laser chemical vapor deposition (LCVD). The resultant textiles exhibited excellent EMI efficiency of 74.2 dB with a thickness of 0.45 mm, Joule heating performance within a low working voltage (V) range of 1–3 V, and fast response time within 20 s. These properties arose from multiple reflections, interfacial polarization, and high conductivity due to the numerous amounts of nanoscale G/SiC heterostructures. More importantly, G/SiC/carbon fibers (CFs) demonstrated well high-temperature resistance with a heat resistance index (THRI) of 380.2 ℃ owing to the protection of a coating layer on the CFs upon oxidation. Meanwhile, the G/SiC/CFs presented good pressure-sensing performance with high sensitivity (S) of 52.93 kPa−1, fast response time of 85 ms, and a wide pressure range of up to 186 kPa. These features imply the potential of the G/SiC/CFs as efficient EMI shielding, electrical heater, and piezoresistive sensor textiles.

Keywords: Joule heating, high-temperature resistance, electromagnetic interference (EMI) shielding, graphene/SiC (G/SiC), pressure-sensing

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Publication history

Received: 20 October 2022
Revised: 15 December 2022
Accepted: 11 January 2023
Published: 09 March 2023
Issue date: April 2023

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© The Author(s) 2023.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (51872212, 51972244, 52102066, and 62204179), the National Key R&D Program of China (2018YFE0103600, 2021YFB3703100), the International Science & Technology Cooperation Program of Hubei Province, China (2022EHB024), and the 111 Project (B13035). It was also supported by the Guangdong Major Project of Basic and Applied Basic Research (2021B0301030001), Key-Area Research and Development Program of Guangdong Province (2021B0707050001, 2019B121204001, and 2020B010181001), the Chaozhou Science and Technology Project (2019PT01), the Self-innovation Research Funding Project of Hanjiang Laboratory (HJL202012A001, HJL202012A002, HJL202012A003), the Major Science and Technology Project in Zhongshan City, Guangdong Province (2019AG029), and the Fundamental Research Funds for the Central Universities (WUT:2022IVA093).

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