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Research Article | Open Access

Achieving a high energy storage density in Ag(Nb,Ta)O3 antiferroelectric films via nanograin engineering

Hongbo CHENGa,b,†, Xiao ZHAIc,†, Jun OUYANGa( ), Limei ZHENGc( ), Nengneng LUOd, Jinpeng LIUa, Hanfei ZHUa, Yingying WANGe, Lanxia HAOe, Kun WANGf
Institute of Advanced Energy Materials and Chemistry, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China
College of Electronic and Optical Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China
School of Physics, Shandong University, Jinan 250100, China
Guangxi Key Laboratory of Processing for Non-ferrous Metallic and Featured Materials, School of Resources, Environment and Materials; Center on Nanoenergy Research, School of Physical Science and Technology, Guangxi University, Nanning 530004, China
Key Laboratory for Liquid-Solid Structure Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan 250061, China
Jinan Cigarette Factory, China Tobacco Shandong Industrial Co., Ltd., Jinan 250104, China

† Hongbo Cheng and Xiao Zhai contributed equally to this work.

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Graphical Abstract

Abstract

Due to its lead-free composition and a unique double polarization hysteresis loop with a large maximum polarization (Pmax) and a small remnant polarization (Pr), AgNbO3-based antiferroelectrics (AFEs) have attracted extensive research interest for electric energy storage applications. However, a low dielectric breakdown field (Eb) limits an energy density and its further development. In this work, a highly efficient method was proposed to fabricate high-energy-density Ag(Nb,Ta)O3 capacitor films on Si substrates, using a two-step process combining radio frequency (RF)-magnetron sputtering at 450 ℃ and post-deposition rapid thermal annealing (RTA). The RTA process at 700 ℃ led to sufficient crystallization of nanograins in the film, hindering their lateral growth by employing short annealing time of 5 min. The obtained Ag(Nb,Ta)O3 films showed an average grain size (D) of ~14 nm (obtained by Debye–Scherrer formula) and a slender room temperature (RT) polarization–electric field (P–E) loop (Pr ≈ 3.8 μC·cm−2 and Pmax ≈ 38 μC·cm−2 under an electric field of ~3.3 MV·cm−1), the P–E loop corresponding to a high recoverable energy density (Wrec) of ~46.4 J·cm−3 and an energy efficiency (η) of ~80.3%. Additionally, by analyzing temperature-dependent dielectric property of the film, a significant downshift of the diffused phase transition temperature (TM2–M3) was revealed, which indicated the existence of a stable relaxor-like AFE phase near the RT. The downshift of the TM2–M3 could be attributed to a nanograin size and residual tensile strain of the film, and it led to excellent temperature stability (20–240 ℃) of the energy storage performance of the film. Our results indicate that the Ag(Nb,Ta)O3 film is a promising candidate for electrical energy storage applications.

Keywords

energy storageantiferroelectrics (AFE)AgNbO3Ag(Nb,Ta)O3film capacitorsnanograin engineering

References

[1]
Palneedi H, Peddigari M, Hwang GT, et al. High-performance dielectric ceramic films for energy storage capacitors: Progress and outlook. Adv Funct Mater 2018, 28: 1803665.
Crossref Google Scholar
[2]
Yao ZH, Song Z, Hao H, et al. Homogeneous/inhomogeneous-structured dielectrics and their energy-storage performances. Adv Mater 2017, 29: 1601727.
Crossref Google Scholar
[3]
Li DX, Zeng XJ, Li ZP, et al. Progress and perspectives in dielectric energy storage ceramics. J Adv Ceram 2021, 10: 675–703.
Crossref Google Scholar
[4]
Zou KL, Dan Y, Xu HJ, et al. Recent advances in lead-free dielectric materials for energy storage. Mater Res Bull 2019, 113: 190–201.
Crossref Google Scholar
[5]
Xu B, Íñiguez J, Bellaiche L. Designing lead-free antiferroelectrics for energy storage. Nat Commun 2017, 8: 15682.
Crossref Google Scholar
[6]
Fu DS, Endo M, Taniguchi H, et al. AgNbO3: A lead-free material with large polarization and electromechanical response. Appl Phys Lett 2007, 90: 252907.
Crossref Google Scholar
[7]
Zhao L, Liu Q, Zhang SJ, et al. Lead-free AgNbO3 anti-ferroelectric ceramics with an enhanced energy storage performance using MnO2 modification. J Mater Chem C 2016, 4: 8380–8384.
Crossref Google Scholar
[8]
Zhao PY, Cai ZM, Wu LW, et al. Perspectives and challenges for lead-free energy-storage multilayer ceramic capacitors. J Adv Ceram 2021, 10: 1153–1193.
Crossref Google Scholar
[9]
Tian Y, Jin L, Zhang HF, et al. Phase transitions in bismuth-modified silver niobate ceramics for high power energy storage. J Mater Chem A 2017, 5: 17525–17531.
Crossref Google Scholar
[10]
Luo NN, Han K, Liu LJ, et al. Lead-free Ag1−3xLaxNbO3 antiferroelectric ceramics with high-energy storage density and efficiency. J Am Ceram Soc 2019, 102: 4640–4647.
Crossref Google Scholar
[11]
Han K, Luo NN, Chen ZP, et al. Simultaneously optimizing both energy storage density and efficiency in a novel lead-free relaxor antiferroelectrics. J Eur Ceram Soc 2020, 40: 3562–3568.
Crossref Google Scholar
[12]
Han K, Luo NN, Mao SF, et al. Realizing high low-electric-field energy storage performance in AgNbO3 ceramics by introducing relaxor behaviour. J Materiomics 2019, 5: 597–605.
Crossref Google Scholar
[13]
Luo NN, Han K, Cabral MJ, et al. Constructing phase boundary in AgNbO3 antiferroelectrics: Pathway simultaneously achieving high energy density and efficiency. Nat Commun 2020, 11: 4824.
Crossref Google Scholar
[14]
Han K, Luo NN, Mao SF, et al. Ultrahigh energy-storage density in A-/B-site co-doped AgNbO3 lead-free antiferroelectric ceramics: Insight into the origin of antiferroelectricity. J Mater Chem A 2019, 7: 26293–26301.
Crossref Google Scholar
[15]
Łukaszewski M, Pawełczyk M, Haňderek J, et al. On the phase transitions in silver niobate AgNbO3. Phase Transitions 1983, 3: 247–257.
Crossref Google Scholar
[16]
Kania A, Roleder K, Łukaszewski M. The ferroelectric phase in AgNbO3. Ferroelectrics 1983, 52: 265–269.
Crossref Google Scholar
[17]
Sciau P, Kania A, Dkhil B, et al. Structural investigation of AgNbO3 phases using X-ray and neutron diffraction. J Phys-Condens Mat 2004, 16: 2795–2810.
Crossref Google Scholar
[18]
Zhao L, Gao J, Liu Q, et al. Silver niobate lead-free antiferroelectric ceramics: Enhancing energy storage density by B-site doping. ACS Appl Mater Inter 2018, 10: 819–826.
Crossref Google Scholar
[19]
Luo NN, Han K, Zhuo FP, et al. Aliovalent A-site engineered AgNbO3 lead-free antiferroelectric ceramics toward superior energy storage density. J Mater Chem A 2019, 7: 14118–14128.
Crossref Google Scholar
[20]
Zhao L, Liu Q, Gao J, et al. Lead-free antiferroelectric silver niobate tantalate with high energy storage performance. Adv Mater 2017, 29: 1701824.
Crossref Google Scholar
[21]
Li S, Nie HC, Wang GS, et al. Significantly enhanced energy storage performance of rare-earth-modified silver niobate lead-free antiferroelectric ceramics via local chemical pressure tailoring. J Mater Chem C 2019, 7: 1551–1560.
Crossref Google Scholar
[22]
Lu ZL, Bao WC, Wang G, et al. Mechanism of enhanced energy storage density in AgNbO3-based lead-free antiferroelectrics. Nano Energy 2021, 79: 105423.
Crossref Google Scholar
[23]
Luo NN, Han K, Zhuo FP, et al. Design for high energy storage density and temperature-insensitive lead-free antiferroelectric ceramics. J Mater Chem C 2019, 7: 4999–5008.
Crossref Google Scholar
[24]
Telli MB, Trolier-McKinstry S, Woodward DI, et al. Chemical solution deposited silver tantalate niobate, Agx(Ta0.5Nb0.5)O3−y, thin films on (111)Pt/Ti/SiO2/(100)Si substrates. J Sol–Gel Sci Techn 2007, 42: 407–414.
Crossref Google Scholar
[25]
Shu L, Zhang X, Li W, et al. Phase-pure antiferroelectric AgNbO3 films on Si substrates: Chemical solution deposition and phase transitions. J Mater Chem A 2022, 10: 12632–12642.
Crossref Google Scholar
[26]
Koh JH, Khartsev SI, Grishin A. Ferroelectric silver niobate-tantalate thin films. Appl Phys Lett 2000, 77: 4416–4418.
Crossref Google Scholar
[27]
Sakurai H, Yamazoe S, Wada T. Ferroelectric and antiferroelectric properties of AgNbO3 films fabricated on (001), (110), and (111)SrTiO3 substrates by pulsed laser deposition. Appl Phys Lett 2010, 97: 042901.
Crossref Google Scholar
[28]
Zhang YL, Li XB, Song JM, et al. AgNbO3 antiferroelectric film with high energy storage performance. J Materiomics 2021, 7: 1294–1300.
Crossref Google Scholar
[29]
Zhao Z, Buscaglia V, Viviani M, et al. Grain-size effects on the ferroelectric behavior of dense nanocrystalline BaTiO3 ceramics. Phys Rev B 2004, 70: 024107.
Crossref Google Scholar
[30]
Johnson-Wilke RL, Wilke RHT, Yeager CB, et al. Phase transitions and octahedral rotations in epitaxial Ag(TaxNb1−x)O3 thin films under tensile strain. J Appl Phys 2015, 117: 085309.
Crossref Google Scholar
[31]
Wang K, Ouyang J, Wuttig M, et al. Superparaelectric (Ba0.95,Sr0.05)(Zr0.2,Ti0.8)O3 ultracapacitors. Adv Energy Mater 2020, 10: 2001778.
Google Scholar
[32]
Wang K, Zhang Y, Wang SX, et al. High energy performance ferroelectric (Ba,Sr)(Zr,Ti)O3 film capacitors integrated on Si at 400 ℃. ACS Appl Mater Inter 2021, 13: 22717–22727.
Crossref Google Scholar
[33]
Zhao YY, Ouyang J, Wang K, et al. Achieving an ultra-high capacitive energy density in ferroelectric films consisting of superfine columnar nanograins. Energy Storage Mater 2021, 39: 81–88.
Crossref Google Scholar
[34]
Valant M, Axelsson AK, Alford N. Review of Ag(Nb,Ta)O3 as a functional material. J Eur Ceram Soc 2007, 27: 2549–2560.
Crossref Google Scholar
[35]
Yan J, Wang YL, Wang CM, et al. Boosting energy storage performance of low-temperature sputtered CaBi2Nb2O9 thin film capacitors via rapid thermal annealing. J Adv Ceram 2021, 10: 627–635.
Crossref Google Scholar
[36]
Lv PP, Yang CH, Qian J, et al. Flexible lead-free perovskite oxide multilayer film capacitor based on (Na0.8K0.2)0.5Bi0.5TiO3/Ba0.5Sr0.5(Ti0.97Mn0.03)O3 for high-performance dielectric energy storage. Adv Energy Mater 2020, 10: 1904229.
Google Scholar
[37]
Wang YY, Yan J, Cheng HB, et al. Low thermal budget lead zirconate titanate thick films integrated on Si for piezo-MEMS applications. Microelectron Eng 2020, 219: 111145.
Crossref Google Scholar
[38]
Tunkasiri T, Rujijanagul G. Dielectric strength of fine grained barium titanate ceramics. J Mater Sci Lett 1996, 15: 1767–1769.
Crossref Google Scholar
[39]
Abbas W, Ho D, Pramanick A. High energy storage efficiency and thermal stability of A-site-deficient and 110-textured BaTiO3–BiScO3 thin films. J Am Ceram Soc 2020, 103: 3168–3177.
Crossref Google Scholar
[40]
Zhao C, Meng XH, Wang W, et al. Energy storage performance of (K,Na)NbO3 ferroelectric thin films with Mn–Ta and Mn–Ti co-doping. Ceram Int 2019, 45: 13772–13779.
Crossref Google Scholar
[41]
Sun YZ, Zhou YP, Lu QS, et al. High energy storage efficiency with fatigue resistance and thermal stability in lead-free Na0.5K0.5NbO3/BiMnO3 solid-solution films. Phys Status Solidi-R 2018, 12: 1700364.
Google Scholar
[42]
Guo F, Shi ZF, Yang B, et al. The role of PN-like junction effects in energy storage performances for Ag2O nanoparticle dispersed lead-free K0.5Na0.5NbO3–BiMnO3 films. Nanoscale 2020, 12: 7544–7549.
Crossref Google Scholar
[43]
Huang Y, Shu L, Zhang SW, et al. Simultaneously achieved high-energy storage density and efficiency in (K,Na)NbO3-based lead-free ferroelectric films. J Am Ceram Soc 2021, 104: 4119–4130.
Crossref Google Scholar
[44]
Won SS, Kawahara M, Kuhn L, et al. BiFeO3-doped (K0.5Na0.5)(Mn0.005,Nb0.995)O3 ferroelectric thin film capacitors for high energy density storage applications. Appl Phys Lett 2017, 110: 152901.
Google Scholar
[45]
Luo BC, Dong HJ, Wang DY, et al. Large recoverable energy density with excellent thermal stability in Mn-modified NaNbO3–CaZrO3 lead-free thin films. J Am Ceram Soc 2018, 101: 3460–3467.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 12 Issue 1,
January 2023
Pages 196-206
DOI: 10.26599/JAC.2023.9220678
Cite this article:
CHENG H, ZHAI X, OUYANG J, et al. Achieving a high energy storage density in Ag(Nb,Ta)O3 antiferroelectric films via nanograin engineering. Journal of Advanced Ceramics, 2023, 12(1): 196-206. https://doi.org/10.26599/JAC.2023.9220678

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Received: 05 July 2022
Revised: 15 October 2022
Accepted: 16 October 2022
Published: 19 December 2022
© The Author(s) 2022.

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