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Research Article | Publishing Language: Chinese | Open Access

Flotation performance and adsorption mechanism of lepidolite by a new bipolar (N—O) ether amine collector

Shuo LIU1,2,3,4Fangxu LI2,3,4Zhiyong GAO1( )Zilin DAI2,3,4
School of Minerals Processing and Bioengineering, Central South University, Changsha Hunan 410083, China
Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou Guangdong 510650, China
State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou Guangdong 510650, China
Guangdong Provincial Key Laboratory of Development and Comprehensive Utilization of Mineral Resources, Guangzhou Guangdong 510650, China
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Abstract

This study proposes a class of ether amine-tridecyl oxy propyl ether amine (TPA) with N—O structure introduced into C—O—C as a flotation collector for the flotation separation of lepidolite. The results of both pure lepidolite and actual ores showed that TPA exhibited better flotation performance under acidic conditions than the traditional collector dodecylamine (DDA). The contact angle test showed that TPA exhibited better hydrophobicity than DDA at different concentrations of collector at pH=5. Zeta potential, infrared spectrum and XPS tests showed that TPA was adsorbed on the surface of lepidolite by electrostatic adsorption. Surface tension and viscosity tests, foam volume and half-life tests together proved that TPA had better foam performance. Therefore, TPA demonstrates promising prospects of application in the flotation of lepidolite due to its hydrophobicity and foam properties.

CLC number: TD953 Document code: A Article ID: 2096-2193(2025)04-0727-11

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Journal of Mining Science and Technology
Pages 727-737

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Cite this article:
LIU S, LI F, GAO Z, et al. Flotation performance and adsorption mechanism of lepidolite by a new bipolar (N—O) ether amine collector. Journal of Mining Science and Technology, 2025, 10(4): 727-737. https://doi.org/10.19606/j.cnki.jmst.2025032

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Received: 25 November 2024
Revised: 05 January 2025
Published: 31 August 2025
© The Author(s) 2025

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).