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Research Article

Facile Synthesis of High-Entropy(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O Nanopowder and Its Electrochemical Properties As Supercapacitor Electrode

Pengchao JIJingxin YANGLin TANFu SUNXinghua SU( )
School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China
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Abstract

High-entropy oxides (HEO) are a novel material with the unique electrochemical properties, which are stabilized due to the high configurational entropy. In this paper, a high-entropy (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder with the sizes of 40–65 nm and a rocksalt structure was synthesized by a polyacrylamide gel method and subsequent calcination at 900 ℃ for 2 h in the presence of a mole ratio of acrylamide/metal cations of 120:1. The results show that the temperature of forming a single-phase (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder decreases with the increase of the mole ratio of acrylamide/metal cations. The HEO nanopowder has a specific capacitance of 402 F/g at a current density of 1 A/g. A rate capability of 62% appears at 20 A/g. The capacitance retention is 61% after 2000 cycles at a current density of 5 A/g. It is indicted that (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder could be used as a prospective electrode material for supercapacitors.

CLC number: TB321 Document code: A Article ID: 0454-5648(2023)01-0124-09

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Journal of the Chinese Ceramic Society
Pages 124-132

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Cite this article:
JI P, YANG J, TAN L, et al. Facile Synthesis of High-Entropy(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O Nanopowder and Its Electrochemical Properties As Supercapacitor Electrode. Journal of the Chinese Ceramic Society, 2023, 51(1): 124-132. https://doi.org/10.14062/j.issn.0454-5648.20220658

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Received: 13 August 2022
Revised: 30 August 2022
Published: 29 November 2022
© 2023 Journal of the Chinese Ceramic Society