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Journal of Electrochemistry 2023, 29(3): 2217008 https://doi.org/10.13208/j.electrochem.2217008
Review | Open Access | Issue | Published: 07 November 2022

A Review on Solid-State Li-S Battery: From the Conversion Mechanism of Sulfur to Engineering Design

Show Author's Information Huan-Huan Jiaa,  Chen-Ji Hua,  Yi-Xiao Zhanga,  Li-Wei Chena,b,c( )
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Electrochemical Energy Device Research Center (SEED) and in-situ Center for Physical Sciences, Shanghai Jiao Tong University, Shanghai, 200240, PR China
Future Battery Research Center, Global Institute of Future Technology, Shanghai Jiao Tong University, Shanghai, 200240, PR China
i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, Suzhou, 215123, PR China
Keywords:
Failure mechanism, Conversion kinetics, Solid-state Li-S batteries, Dynamically stable interface, Engineering design
Cite this article:
Jia H-H, Hu C-J, Zhang Y-X, et al. A Review on Solid-State Li-S Battery: From the Conversion Mechanism of Sulfur to Engineering Design. Journal of Electrochemistry , 2023, 29(3): 2217008. https://doi.org/10.13208/j.electrochem.2217008
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Abstract Full text About this article

Lithium-sulfur (Li-S) batteries attract sustained attention because of their ultrahigh theoretical energy density of 2567 Wh·kg–1 and the actual value over 600 Wh·kg–1. Solid-state Li-S batteries (SSLSBs) emerge in the recent two decades because of the enhanced safety when compared to the liquid system. As for the SSLSBs, except for the difference in the conversion mechanism induced by the cathode materials themselves, the physical-chemical property of solid electrolytes (SEs) also significantly affects their electrochemical behaviors. On account of various reported Li-S batteries, the advantages and disadvantages in performance and the failure mechanism are discussed in this review. Based on the problems of the reported SSLSBs such as lower energy density and faster capacity fading, the strategies of building high-performance SSLSBs are classified. The review aims to afford fundamental understanding on the conversion mechanism of sulfur and engineering design at full-cell level, so as to promote the development of SSLSBs.


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About this article

A Review on Solid-State Li-S Battery: From the Conversion Mechanism of Sulfur to Engineering Design

Show Author's information Huan-Huan Jiaa, Chen-Ji Hua, Yi-Xiao Zhanga, Li-Wei Chena,b,c( )
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Electrochemical Energy Device Research Center (SEED) and in-situ Center for Physical Sciences, Shanghai Jiao Tong University, Shanghai, 200240, PR China
Future Battery Research Center, Global Institute of Future Technology, Shanghai Jiao Tong University, Shanghai, 200240, PR China
i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, Suzhou, 215123, PR China

Abstract

Lithium-sulfur (Li-S) batteries attract sustained attention because of their ultrahigh theoretical energy density of 2567 Wh·kg–1 and the actual value over 600 Wh·kg–1. Solid-state Li-S batteries (SSLSBs) emerge in the recent two decades because of the enhanced safety when compared to the liquid system. As for the SSLSBs, except for the difference in the conversion mechanism induced by the cathode materials themselves, the physical-chemical property of solid electrolytes (SEs) also significantly affects their electrochemical behaviors. On account of various reported Li-S batteries, the advantages and disadvantages in performance and the failure mechanism are discussed in this review. Based on the problems of the reported SSLSBs such as lower energy density and faster capacity fading, the strategies of building high-performance SSLSBs are classified. The review aims to afford fundamental understanding on the conversion mechanism of sulfur and engineering design at full-cell level, so as to promote the development of SSLSBs.

Keywords: Failure mechanism, Conversion kinetics, Solid-state Li-S batteries, Dynamically stable interface, Engineering design

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Received: 19 September 2022
Revised: 10 October 2022
Accepted: 04 November 2022
Published: 07 November 2022
Issue date: March 2023

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© 2023 Xiamen University and Chinese Chemical Society.

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Acknowledgements

This work is supported by the National Key R&D Program of China (2021YFB3800300) and China Postdoctoral Science Foundation (BX20220199).

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This is an open access article under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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