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Review | Open Access

Cellulose Nanocrystals-based Chiroptical Materials

State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, Jilin Province, 130012, China
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Abstract

Chiroptical materials are widely used in photonic devices, enantioselective catalysis and bio-sensors. Cellulose-base chiroptical materials with multilength scale structural hierarchy and unique light manipulation ability found in nature provide inspiration for materials design. Cellulose nanocrystals (CNC) display twisted rod morphology and hierarchical chirality. Leveraging the evaporation-induced self-assembly of negatively charged CNC, a broad realm of CNC-based chiroptical materials featuring one-dimensional photonic bandgap and novel chiroptical properties have been developed, which are of scientific and technological significance. Here we presented a brief overview on CNC-based chiroptical materials by evaporation-induced self-assembly, showed energy and chirality transfer in a host-guest environment leading to photonic bandgap modulation of optoelectronic properties, outlined novel chiroptical phenomena and their underlying principles, and demonstrated the application potentials of the CNC-based chiroptical materials.

Keywords

cellulose nanocrystalschiroptical materialsphotonic bandgapsoptoelectronicsenergy and chirality transfer

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Paper and Biomaterials
Volume 5 Issue 3,
July 2020
Pages 14-30
DOI: 10.12103/j.issn.2096-2355.2020.03.002
Cite this article:
Tao J, Xu Y. Cellulose Nanocrystals-based Chiroptical Materials. Paper and Biomaterials, 2020, 5(3): 14-30. https://doi.org/10.12103/j.issn.2096-2355.2020.03.002

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Received: 29 April 2020
Accepted: 14 May 2020
Published: 15 July 2020
© 2020 Paper and Biomaterials

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
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