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Paper and Biomaterials 2020, 5(3): 14-30 https://doi.org/10.12103/j.issn.2096-2355.2020.03.002
Review | Open Access | Issue | Published: 15 July 2020

Cellulose Nanocrystals-based Chiroptical Materials

Show Author's Information Jiawei Tao,  Yan Xu( )
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, Jilin Province, 130012, China
Keywords:
optoelectronics, cellulose nanocrystals, chiroptical materials, photonic bandgaps, energy and chirality transfer
Cite this article:
Tao J, Xu Y. Cellulose Nanocrystals-based Chiroptical Materials. Paper and Biomaterials, 2020, 5(3): 14-30. https://doi.org/10.12103/j.issn.2096-2355.2020.03.002
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Abstract Full text About this article

Chiroptical materials are widely used in photonic devices, enantioselective catalysis and bio-sensors. Cellulose-base chiroptical materials with multilength scale structural hierarchy and unique light manipulation ability found in nature provide inspiration for materials design. Cellulose nanocrystals (CNC) display twisted rod morphology and hierarchical chirality. Leveraging the evaporation-induced self-assembly of negatively charged CNC, a broad realm of CNC-based chiroptical materials featuring one-dimensional photonic bandgap and novel chiroptical properties have been developed, which are of scientific and technological significance. Here we presented a brief overview on CNC-based chiroptical materials by evaporation-induced self-assembly, showed energy and chirality transfer in a host-guest environment leading to photonic bandgap modulation of optoelectronic properties, outlined novel chiroptical phenomena and their underlying principles, and demonstrated the application potentials of the CNC-based chiroptical materials.


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About this article

Cellulose Nanocrystals-based Chiroptical Materials

Show Author's information Jiawei Tao, Yan Xu( )
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, Jilin Province, 130012, China

Abstract

Chiroptical materials are widely used in photonic devices, enantioselective catalysis and bio-sensors. Cellulose-base chiroptical materials with multilength scale structural hierarchy and unique light manipulation ability found in nature provide inspiration for materials design. Cellulose nanocrystals (CNC) display twisted rod morphology and hierarchical chirality. Leveraging the evaporation-induced self-assembly of negatively charged CNC, a broad realm of CNC-based chiroptical materials featuring one-dimensional photonic bandgap and novel chiroptical properties have been developed, which are of scientific and technological significance. Here we presented a brief overview on CNC-based chiroptical materials by evaporation-induced self-assembly, showed energy and chirality transfer in a host-guest environment leading to photonic bandgap modulation of optoelectronic properties, outlined novel chiroptical phenomena and their underlying principles, and demonstrated the application potentials of the CNC-based chiroptical materials.

Keywords: optoelectronics, cellulose nanocrystals, chiroptical materials, photonic bandgaps, energy and chirality transfer

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Publication history
Copyright
Acknowledgements
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Publication history

Received: 29 April 2020
Accepted: 14 May 2020
Published: 15 July 2020
Issue date: July 2020

Copyright

© 2020 Paper and Biomaterials

Acknowledgements

The authors are grateful for the financial support from NNSF China (grant nos. 21975095, 21671079, and 21373100), 111 project (grant no. B17020), JLU international co-advisorship program (grant no. 419020201362), JLU international collaboration program (grant no. 45119031C015) and the State key laboratory of inorganic synthesis and preparative chemistry of JLU (grant no. 1G3194101461).

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This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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