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Publishing Language: Chinese | Open Access

Influence of Inorganic Salts on the Dissolution Temperature of Ammonium Nitrate and the Explosive Performance of Expanded Ammonium Nitrate Explosives

Yan LI1Xiaorong CUI1,2Rui LI1,2( )Quan WANG1Minghang HU1Rui SUN1Yajing CHEN1
School of Chemical and Blasting Engineering, Anhui University of Science and Technology,Huainan 232001, Anhui, China
Hongda Civil Explosives Group Co., Ltd., Guangzhou 510623, Guangdong, China
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Abstract

In order to explore the influence of inorganic salts on the dissolution temperature of ammonium nitrate and the explosive performance of expanded ammonium nitrate explosives, the inorganic salts of 2%, 4% and 6% of NaCl, KCl, NaNO3 and KNO3 respectively were used to replace the ammonium nitrate content in the expanded ammonium nitrate explosives, and the explosion performance (including the detonation velocity, the fierceness, and the work ability were measured). The results show that when the mass fraction of inorganic salt is 2%, the dissolution temperature is 8 to 12 ℃ lower than that of the traditional puffed ammonium nitrate formula explosives; the expanded ammonium nitrate explosives with NaNO3 and KNO3 is 120−150 m/s higher than the traditional formula, and NaCl and KCl are reduced by 150−850 m/s; lead column compression of NaNO3 and KNO3 increased by 0.62−1.90 mm, and NaCl and KCl decreased by 0.06−2.55 mm; the peak overpressure of NaNO3 and KCl increased by 0.02−0.78 kPa, and NaCl and KNO3 inorganic salts decreased by 5.02−19.57 kPa. For every 2% increase in the mass fraction of inorganic salt substitution, the dissolution temperature decreases by 7 to 10 ℃; the detonation velocity decreases by 100 to 300 m/s; lead column compression decreases by 0.08 to 0.73 mm; and the peak overpressure decrease by 1.77 to 13.5 kPa. In practice, a small quantity of NaNO3 can be added to the expanded ammonium nitrate explosives, which is not only conducive to reducing the dissolution temperature of ammonium nitrate, but also enhances the explosive performance of explosives.

CLC number: O389; TJ55; O521.9 Document code: A

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Chinese Journal of High Pressure Physics

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Cite this article:
LI Y, CUI X, LI R, et al. Influence of Inorganic Salts on the Dissolution Temperature of Ammonium Nitrate and the Explosive Performance of Expanded Ammonium Nitrate Explosives. Chinese Journal of High Pressure Physics, 2025, 39(4). https://doi.org/10.11858/gywlxb.20240914

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Received: 17 October 2024
Revised: 16 November 2024
Published: 05 April 2025
© 2025 Editorial Office of Chinese Journal of High Pressure Physics

This is an open access article under the CC BY-NC-ND license (https://creativecommons.org/licenses/by-nc/4.0/)