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Continental shale oil represents a strategic replacement for improving reserves and well productivity in China. However, its development is facing two major challenges: the limited mobility of hydrocarbon fluids and poor reservoir fracability. To address these issues, we explore the mechanism and application of supercritical carbon dioxide (SC-CO2) hybrid fracturing for shale oil in the Jiyang Depression, Shengli oilfield, through an array of tests, including the SC-CO2-water-rock interactions, diffusion and displacement, true triaxial compression, and triaxial compression. The results indicate that dissolution with SC-CO2 can increase shale porosity by 1 ~ 5 times, resulting in the predominance of mesopores and macropores. In addition, the fractures get enlarged as the reaction goes on. Specifically, the fracture width increased from 399 nm after 2-hour dissolution to 1.535 μm after 12 h, representing a fourfold increase in width, and concurrent permeability increase by 1 ~ 3 orders of magnitude. The SC-CO2-invovled oil extraction achieved an efficiency of up to 24 %, with minimal effects observed beyond 30 h. Compared to dry shales, the tensile strength of shales subjected to SC-CO2-water treatment decreased by 31 %. Unlike dry fracturing, SC-CO2 hybrid fracturing can create bedding-parallel fractures by removing barriers to enhance bedding connectivity, which tend to form a complex fracture network in combination with subsequent hydraulic fractures. Grounded on theoretical research in lab, we conduct field tests of SC-CO2 fracturing. The test results indicate that, in well Y-1, the average fracture propagation pressure for all sections decreased from 103.4 MPa before CO2 injection to 100.5 MPa after CO2 injection. Additionally, microseismic events recorded during fracturing in well Y-1 became more concentrated, with an average event number of 160.8 and an average effective stimulated rock volume (SRV) of 647800 m3 overall. Moreover, both the viscosity and density of reservoir fluids decreased, resulting in an improvement in their mobility.
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