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Research paper | Open Access

Enhanced energy storage properties and antiferroelectric stability of Mn-doped NaNbO3-CaHfO3 lead-free ceramics: Regulating phase structure and tolerance factor

Yang Yina,1, Jing-Ru Yua,1, Yu-Cheng Tanga, Ai-Zhen Songa, Huan Liua, Dong Yangb( ), Jing-Feng Lib( ), Lei Zhaoc( ), Bo-Ping Zhanga( )
School of Materials Science and Engineering, University of Science and Technology Beijing, 100083, Beijing, China
School of Materials Science and Engineering, Tsinghua University, 100084, Beijing, China
College of Physics Science and Technology, Hebei University, 071002, Baoding, China

1 These authors contributed equally.]]>

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Graphical Abstract

Abstract

NaNbO3-based ceramics usually show ferroelectric-like P-E loops at room temperature due to the irreversible transformation of the antiferroelectric orthorhombic phase to ferroelectric orthorhombic phase, which is not conducive to energy storage applications. Our previous work found that incorporating CaHfO3 into NaNbO3 can stabilize its antiferroelectric phase by reducing the tolerance factor (t), as indicated by the appearance of characteristic double P-E loops. Furthermore, a small amount of MnO2 addition effectively regulate the phase structure and tolerance factor of 0.94NaNbO3-0.06CaHfO3 (0.94NN-0.06CH), which can further improve the stability of antiferroelectricity. The XRD and XPS results reveal that the Mn ions preferentially replace A-sites and then B-sites as increasing MnO2. The antiferroelectric orthorhombic phase first increases and then decreases, while the t shows the reversed trend, thus an enhanced antiferroelectricity and the energy storage density Wrec of 1.69 J/cm3 at 240 kV/cm are obtained for 0.94NN-0.06CH-0.5%MnO2(in mass fraction). With the increase of Mn content to 1.0 % from 0.5 %, the efficiency increases to 81 % from 45 %, although the energy storage density decreases to 1.31 J/cm3 due to both increased tolerance factor and non-polar phase.

Keywords

NaNbO3Antiferroelectric ceramicTolerance factorEnergy-storage density

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Journal of Materiomics
Volume 8 Issue 3,
May 2022
Pages 611-617
DOI: 10.1016/j.jmat.2021.11.013
Cite this article:
Yin Y, Yu J-R, Tang Y-C, et al. Enhanced energy storage properties and antiferroelectric stability of Mn-doped NaNbO3-CaHfO3 lead-free ceramics: Regulating phase structure and tolerance factor. Journal of Materiomics, 2022, 8(3): 611-617. https://doi.org/10.1016/j.jmat.2021.11.013

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Received: 23 September 2021
Revised: 02 November 2021
Accepted: 22 November 2021
Published: 25 November 2021
© 2021 The Chinese Ceramic Society.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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