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Full Length Article | Open Access

Graphene–calcium carbonate coating to improve the degradation resistance and mechanical integrity of a biodegradable implant

Lokesh Choudharya,1Parama Chakraborty Banerjeeb,1( )R.K. Singh Ramana,b( )Derrek E. Loboa,cChristopher D. EastondMainak Majumdera,cFrank WitteeJörg F. Löfflerf
Department of Mechanical and Aerospace Engineering, Monash University, Clayton Campus, Melbourne, VIC 3800, Australia
Department of Chemical and Biological Engineering, Monash University, Clayton Campus, Melbourne, VIC 3800, Australia
Nanoscale Science and Engineering Laboratory (NSEL), Bldg 37, Monash University, Clayton Campus, Melbourne, VIC 3800, Australia
CSIRO Materials Science and Engineering, Bayview Avenue, Clayton, VIC 3168, Australia
Julius Wolff Institute and Berlin Brandenburg Center for Regenerative Therapies, Charité – Universitätsmedizin Berlin, Augustenburger Platz 1, 13353 Berlin, Germany
Laboratory of Metal Physics and Technology, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland

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Abstract

Biodegradable implants are critical for regenerative orthopaedic procedures, but they may suffer from too fast corrosion in human-body environment. This necessitates the synthesis of a suitable coating that may improve the corrosion resistance of these implants without compromising their mechanical integrity. In this study, an AZ91 magnesium alloy, as a representative for a biodegradable Mg implant material, was modified with a thin reduced graphene oxide (RGO)-calcium carbonate (CaCO3) composite coating. Detailed analytical and in-vitro electrochemical characterization reveals that this coating significantly improves the corrosion resistance and mechanical integrity, and thus has the potential to greatly extend the related application field.

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Journal of Magnesium and Alloys
Pages 394-404

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Cite this article:
Choudhary L, Banerjee PC, Singh Raman R, et al. Graphene–calcium carbonate coating to improve the degradation resistance and mechanical integrity of a biodegradable implant. Journal of Magnesium and Alloys, 2024, 12(1): 394-404. https://doi.org/10.1016/j.jma.2023.12.012

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Received: 23 April 2023
Revised: 19 October 2023
Accepted: 19 December 2023
Published: 17 January 2024
© 2024 Chongqing University.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/) Peer review under responsibility of Chongqing University