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Full Length Article | Open Access

Shielding AZ91D-1%Ca from corrosion through ultrasound melt treatment: A study for stent design

I.V. Gomesa,bM. Pachecoc,dM. NienabereS.C. Nevesc,dD. MeifA. Barrosc,dR.L. Reisc,dJ.L. Alvesa,bH. Pugaa,b( )
CMEMS – UMinho, University of Minho, Guimarães, Portugal
LABBELS –Associate Laboratory, Braga, Guimarães, Portugal
B’s Research Group - Research Institute on Biomaterials, Biodegradables and Biomimetics, University of Minho, Headquarters of the European Institute of Excellence on Tissue Engineering and Regenerative Medicine, Avepark - Parque de Ciência e Tecnologia, Barco Guimarães, Portugal
ICVS/3B’s-PT Government Associate Laboratory, Braga, Guimarães, Portugal
Institute of Material and Process Design, Helmholtz-Zentrum Hereon, Geesthacht 21502, Germany
School of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy, Zhengzhou University, Zhengzhou 450001, China
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Abstract

Magnesium-based materials show great potential for producing biodegradable stents, but their high corrosion rates are a roadblock.

This study investigates whether ultrasound melt treatment can change the corrosion response of an extruded AZ91D-1.0%Ca (wt.%) in Earle’s Balanced Salt Solution by tailoring the intermetallics’ morphology in the as-extruded state.

The results showed that the wires from ultrasound-treated ingots corroded faster than non-treated ones in immersion for up to 6 hours. This trend shifted for longer periods, and ultrasound-treated material showed lower corrosion rates and uniform corrosion, while the non-treated material displayed localized corrosion signs. Tensile testing of the wires demonstrated that immersion in EBSS lowered the tensile strength and elongation at fracture due to material degradation, regardless of the processing route. Nonetheless, this decline was sharper in the non-treated material.

These findings suggest that ultrasound melt processing can be a promising method for improving the corrosion resistance of magnesium-based materials, paving the way for their use in manufacturing biodegradable stents.

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Journal of Magnesium and Alloys
Pages 2901-2915

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Cite this article:
Gomes I, Pacheco M, Nienaber M, et al. Shielding AZ91D-1%Ca from corrosion through ultrasound melt treatment: A study for stent design. Journal of Magnesium and Alloys, 2023, 11(8): 2901-2915. https://doi.org/10.1016/j.jma.2023.07.013

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Received: 06 April 2023
Revised: 21 July 2023
Accepted: 24 July 2023
Published: 01 September 2023
© 2023 Chongqing University.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/) Peer review under responsibility of Chongqing University