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Research Article | Open Access

CdTe QDs@SiO2 composite material for efficient photocatalytic degradation of tetracycline composites

Taihang Zhoua, Fen Qiaoa ( ), Sen Qiana, Shoaib Muhammada, Haitao Lib, Yanzhen Liua( )
School of Energy & Power Engineering, Jiangsu University, Zhenjiang, 212013, China
Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, China
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HIGHLIGHTS

· The heterogeneous nodules of CdTe QDs@SiO2 were prepared by reversephase microemulsion method.

· By controlling the reflux times of CdTe QDs and adjusting the number of CdTe QDs, the photocatalytic degradation efficiency of SiO2 is greatly improved.

· The thermal injection method effectively regulates the CdTe QDs@SiO2 surface structure, thus achieving efficient tetracycline degradation.

Abstract

In the contemporary context, tetracycline is widely utilized as a prevalent antibiotic in various facets of life. However, the excessive use of antibiotics has caused visible environmental consequences. Henceforth, the scientific community has increasingly focused on developing catalysts that exhibit exceptional efficacy in the proficient degradation of tetracycline. In this study, a novel nanomaterial was developed to encapsulate CdTe quantum dots (QDs) with a SiO2 shell. The distinct synthesis approach generated a composite material that showed heterogeneity and considerably increased the contact area with contaminants. Consequently, the transfer of photoelectron to the SiO2 spheres was significantly improved, leading to a more efficient separation during the catalytic process. The study investigated how different factors, such as the loading of the catalyst, the initial concentration of tetracycline, pH levels, and the wight ratio of CdTe QDs (SiO2 + CdTe QDs) affected the effectiveness of photocatalytic tetracycline degradation. The findings indicated that the optimal degradation efficiency was observed at a catalyst concentration of 0.25 g/L and a solution pH of 9, leading to an impressive degradation rate of 96% within a mere 2 h timeframe.

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References

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Green Chemical Engineering
Pages 533-542

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Cite this article:
Zhou T, Qiao F, Qian S, et al. CdTe QDs@SiO2 composite material for efficient photocatalytic degradation of tetracycline composites. Green Chemical Engineering, 2024, 5(4): 533-542. https://doi.org/10.1016/j.gce.2024.01.004

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Received: 24 October 2023
Revised: 17 January 2024
Accepted: 24 January 2024
Published: 02 February 2024
© 2024 Institute of Process Engineering, Chinese Academy of Sciences.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).