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Impact–sliding caused by random vibrations between tubes and supports can affect the operation of heat exchangers. In addition, a corrosive environment can cause damage, accelerating the synergism of corrosion and wear. Therefore, the focus of this work was the impact–sliding fretting tribocorrosion behavior of 316L heat exchanger tubes at different halide concentrations. A device system incorporating the in situ electrochemical measurements of impact–sliding fretting corrosion wear was constructed, and experiments on 316L heat exchanger tubes in sodium chloride (NaCl) solution with different concentrations (0.0, 0.1, 0.5, 1.0, 3.5, and 5.0 wt%) were carried out. The synergism between wear and corrosion was also calculated and analyzed. The wear and damage mechanisms were elucidated by correlating the corrosion–wear synergism, morphologies, and material loss rates. The results indicated that the stable wear stage occurred at approximately 9–12 h, after which the corrosion current increased with the expansion of the wear area. As the halide concentration increased, the scale of damage on the wear scars gradually decreased, changing from being dominated by cracks, delaminations, and grooves to being dominated by scratches, microgrooves, and holes. There was an obvious positive synergism between wear and corrosion. The material loss was dominated by pure mechanical wear and wear enhanced by corrosion, but corrosion enhanced by wear contributed more than tangential sliding fretting corrosion. The total mass loss increased gradually in the range of 0.0–0.5 wt% and decreased in the range of 0.5–5.0 wt%. Large-scale damage enhanced by corrosivity and small-scale damage reduced by lubricity dominated the material loss at low and high concentrations, respectively.


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Impact–sliding fretting tribocorrosion behavior of 316L stainless steel in solution with different halide concentrations

Show Author's information Xu MA1Wei TAN1,2Remy BONZOM3Xue MI4Guorui ZHU1,2( )
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
Zhejiang Institute of Tianjin University, Ningbo 315201, China
Electricité de France R&D, Materials and Mechanics of Components Department, Moret sur Loing 77818, France
Nuclear Power Institute of China, Chengdu 610044, China

Abstract

Impact–sliding caused by random vibrations between tubes and supports can affect the operation of heat exchangers. In addition, a corrosive environment can cause damage, accelerating the synergism of corrosion and wear. Therefore, the focus of this work was the impact–sliding fretting tribocorrosion behavior of 316L heat exchanger tubes at different halide concentrations. A device system incorporating the in situ electrochemical measurements of impact–sliding fretting corrosion wear was constructed, and experiments on 316L heat exchanger tubes in sodium chloride (NaCl) solution with different concentrations (0.0, 0.1, 0.5, 1.0, 3.5, and 5.0 wt%) were carried out. The synergism between wear and corrosion was also calculated and analyzed. The wear and damage mechanisms were elucidated by correlating the corrosion–wear synergism, morphologies, and material loss rates. The results indicated that the stable wear stage occurred at approximately 9–12 h, after which the corrosion current increased with the expansion of the wear area. As the halide concentration increased, the scale of damage on the wear scars gradually decreased, changing from being dominated by cracks, delaminations, and grooves to being dominated by scratches, microgrooves, and holes. There was an obvious positive synergism between wear and corrosion. The material loss was dominated by pure mechanical wear and wear enhanced by corrosion, but corrosion enhanced by wear contributed more than tangential sliding fretting corrosion. The total mass loss increased gradually in the range of 0.0–0.5 wt% and decreased in the range of 0.5–5.0 wt%. Large-scale damage enhanced by corrosivity and small-scale damage reduced by lubricity dominated the material loss at low and high concentrations, respectively.

Keywords: tribocorrosion, fretting wear, 316L stainless steel, impact–sliding, halide concentration

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Publication history

Received: 28 September 2022
Revised: 06 December 2022
Accepted: 05 January 2023
Published: 20 June 2023
Issue date: December 2023

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© The author(s) 2023.

Acknowledgements

The work was funded by the Materials Ageing Institute. Thanks to Dr. Kai GUO from School of Environmental and Chemical Engineering, Yanshan University, China, for his technical support.

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