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Research Article | Open Access

A robust membrane with dual superlyophobicity for solving water-caused lubricant deterioration and water contamination

Siyang ZHAO1,2Chenggong XU1,2Jiaxu ZHANG3Yongmin LIANG1,4Weimin LIU1( )Jinxia HUANG1( )Zhiguang GUO1,5( )
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
University of Chinese Academy of Sciences, Beijing 100049, China
School of Engineering and Technology, China University of Geosciences (Beijing), Beijing 100083, China
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan 430062, China
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Abstract

Lubricants are often contaminated by water in different ways. Water-polluted lubricants extremely accelerate wear corrosion, leading to the deterioration of lubricity performance. Recently, multiphase media superwettability has been developed to endow one surface with compatible functions, such as on-demand separation of oily wastewater. However, realizing the robustness of the dual superlyophobic surface to solve water-caused lubricant deterioration and water contamination as needed remains challenges. Herein, a robust dual superlyophobic membrane is presented to realize on-demand separation for various lubricant–water emulsions. Compared to pure lubricants, the purified lubricants have equivalent tribology performance, which are much better than that of water-polluted lubricants. The as-prepared membrane maintains dual superlyophobicity, high-efficient for water or lubricant purification, and excellent tribology performance of the purified lubricant, even after immersion in hot liquids for 24 h, multicycle separation, and sandpaper abrasion for 50 cycles. Water-polluted lubricant extremely accelerates wear corrosion to promote catalytic dehydrogenation of lubricants, generating too much harmful carbon-based debris. This work shows great guiding significance for recovering the tribology performance of water-polluted lubricants and purifying water by the dual superlyophobic membrane.

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Friction
Pages 1442-1454
Cite this article:
ZHAO S, XU C, ZHANG J, et al. A robust membrane with dual superlyophobicity for solving water-caused lubricant deterioration and water contamination. Friction, 2023, 11(8): 1442-1454. https://doi.org/10.1007/s40544-022-0677-7

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Received: 16 April 2022
Revised: 13 June 2022
Accepted: 19 July 2022
Published: 17 January 2023
© The author(s) 2022.

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