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Review Article | Open Access

A review of current understanding in tribochemical reactions involving lubricant additives

Yan CHEN1Peter RENNER2Hong LIANG1,2( )
Department of Materials Science and Engineering, Texas A&M University, College Station 77843, USA
J. Mike Walker ’66 Department of Mechanical Engineering, Texas A&M University, College Station 77843, USA
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Graphical Abstract


Lubricants have played important roles in friction and wear reduction and increasing efficiency of mechanical systems. To optimize tribological performance, chemical reactions between a lubricant and a substrate must be designed strategically. Tribochemical reactions are chemical reactions enabled or accelerated by mechanical stimuli. Tribochemically activated lubricant additives play important roles in these reactions. In this review, current understanding in mechanisms of chemical reactions under shear has been discussed. Additives such as oil-soluble organics, ionic liquids (ILs), and nanoparticles (NPs) were analyzed in relation to the tribochemical reaction routes with elements in metallic substrates. The results indicated that phosphorus, sulfur, fluorine, and nitrogen are key elements for tribochemical reactions. The resulting tribofilms from zinc dithiophosphates (ZDDP) and molybdenum dithiocarbamate (MoDTC) have been widely reported, yet that from ILs and NPs need to investigate further. This review serves as a reference for researchers to design and optimize new lubricants.


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Cite this article:
CHEN Y, RENNER P, LIANG H. A review of current understanding in tribochemical reactions involving lubricant additives. Friction, 2023, 11(4): 489-512.








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Received: 03 April 2021
Revised: 25 November 2021
Accepted: 21 April 2022
Published: 18 November 2022
© The author(s) 2022.

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