High temperature induced "glaze" layer formed in HVOF-sprayed NiCrWMoCuCBFe coating and its wear reduction mechanism

Yijing WANG; Xiaoqin ZHAO; Enkang HAO; Zhenyu BU; Yulong AN; Huidi ZHOU; Jianmin CHEN

doi:10.1007/s40544-021-0557-6

Friction 2022, 10(9): 1424-1438 https://doi.org/10.1007/s40544-021-0557-6

Research Article |

Open Access | Issue | Published: 19 January 2022

High temperature induced "glaze" layer formed in HVOF-sprayed NiCrWMoCuCBFe coating and its wear reduction mechanism

Show Author's Information Hide Author's Information Yijing WANG^{¹^,²}, Xiaoqin ZHAO^¹(

), Enkang HAO^{¹^,²}, Zhenyu BU^{¹^,²}, Yulong AN^{¹^,²}(

), Huidi ZHOU^{¹^,²}, Jianmin CHEN^{¹^,²}

1State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Keywords:

mechanical properties, high temperature, wear and friction, NiCrWMoCuCBFe coating, in-situ oxidation, glaze layer

Cite this article:

WANG Y, ZHAO X, HAO E, et al. High temperature induced "glaze" layer formed in HVOF-sprayed NiCrWMoCuCBFe coating and its wear reduction mechanism. Friction, 2022, 10(9): 1424-1438. https://doi.org/10.1007/s40544-021-0557-6

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Abstract Full text About this article

Abstract

The in-situ formation of oxides on alloy surface induced by high temperature can effectively reduce wear and resist oxidation. In consideration of the solid solution strengthening effect and great oxidation resistance of additional elements at elevated temperature, the NiCrWMoCuCBFe coating was prepared by high velocity oxygen flame (HVOF) spraying technology, and its tribological behavior was scrutinized from 25 to 800 °C. By means of high temperature Vickers hardness tester and high temperature X-ray diffractometer, the mechanical properties and microstructures of NiCrWMoCuCBFe coating were measured. And the effect of the mechanical properties and microstructures of the coating on tribological performance was discussed in detail. The results showed both its friction coefficient (0.37) and wear rate (5.067 × 10⁻⁶ mm³·N⁻¹·m⁻¹) at 800 °C were the lowest, which was mainly related to the formation of "glaze" layer on the coating surface at high temperature. The glaze layer consisted of two parts, which were NiCr₂O₄ oxide film with the ability of interlaminar slip formed in the outer layer and nano-grains existed in the inner layer. Worth mentioning, these nano-grains provided bearing capability while the oxide film was vital to reduce wear rate and friction coefficient. As the ambient temperature increased, many hard oxides were produced on the wear scars, including NiO, Cr₂O₃, MoO₃, and Mo₂C. They can improve tribological and mechanical properties of NiCrWMoCuCBFe coating at a wide temperature range.

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High temperature induced "glaze" layer formed in HVOF-sprayed NiCrWMoCuCBFe coating and its wear reduction mechanism

Show Author's information Hide Author's Information Yijing WANG^{¹^,²}, Xiaoqin ZHAO^¹(

), Enkang HAO^{¹^,²}, Zhenyu BU^{¹^,²}, Yulong AN^{¹^,²}(

), Huidi ZHOU^{¹^,²}, Jianmin CHEN^{¹^,²}

1State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

2Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Keywords: mechanical properties, high temperature, wear and friction, NiCrWMoCuCBFe coating, in-situ oxidation, glaze layer

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Acknowledgements

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Publication history

Received: 14 May 2021

Revised: 29 June 2021

Accepted: 20 September 2021

Published: 19 January 2022

Issue date: September 2022

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51771214) and the Youth Innovation Promotion Association of Chinese Academy of Sciences (No. 2014378).

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