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We prepared a graphene/ionic liquid (G/IL) composite material by the hybridization of G and an IL for use as a lubricating oil additive. The friction coefficient and wear volume of a base oil containing 0.04 wt% of the G/IL composite was reduced by 45% and 90%, respectively. Furthermore, the base oil containing the G/IL composite exhibited better lubricating properties than the base oil containing G, IL, or a mixture of IL and G at the same mass fraction. A synergistic lubrication mechanism was also revealed. The G/IL composite was adsorbed and deposited on the wear surface, forming a more ordered protective film and a unique tribochemical reaction film during rubbing. Therefore, the G/IL composite exhibited the synergistic lubricating effects of G and IL, which significantly improved the lubricating performance of the base oil. This study also suggested a way to limit the out-of-plane puckering of G at the macroscale.


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Synergistic lubricating effect of graphene/ionic liquid composite material used as an additive

Show Author's information Lincong LIU1Ming ZHOU1( )Youtang MO1Pengpeng BAI2Qilin WEI3Long JIN1Shengli YOU1Mingyue WANG1Liangchuan LI1Xin CHEN1Xiao LI4Yu TIAN2
School of Mechanical and Transportation Engineering, Guangxi University of Science and Technology, Liuzhou 545006, China
State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China
Department of Electromechain and Automotive Engineering, Liuzhou City Vocational College, Liuzhou 535006, China
Chengdu Carbon Co., Ltd., Chengdu 610100, China

Abstract

We prepared a graphene/ionic liquid (G/IL) composite material by the hybridization of G and an IL for use as a lubricating oil additive. The friction coefficient and wear volume of a base oil containing 0.04 wt% of the G/IL composite was reduced by 45% and 90%, respectively. Furthermore, the base oil containing the G/IL composite exhibited better lubricating properties than the base oil containing G, IL, or a mixture of IL and G at the same mass fraction. A synergistic lubrication mechanism was also revealed. The G/IL composite was adsorbed and deposited on the wear surface, forming a more ordered protective film and a unique tribochemical reaction film during rubbing. Therefore, the G/IL composite exhibited the synergistic lubricating effects of G and IL, which significantly improved the lubricating performance of the base oil. This study also suggested a way to limit the out-of-plane puckering of G at the macroscale.

Keywords: synergistic lubrication, grapheme (G), ionic liquid (IL), protective films, out-of-plane puckering mechanism

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Publication history
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Publication history

Received: 20 May 2020
Revised: 28 July 2020
Accepted: 10 August 2020
Published: 21 November 2020
Issue date: December 2021

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© The author(s) 2020

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 12062002), Guangxi Natural Science Foundation (Grant No. 2018GXNSFAA138174), and the Science and Technology Development Plan of Liuzhou (No. 2018CB10508).

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