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Metal-matrix self-lubricating composites can exhibit excellent tribological properties owing to the release of solid lubricant from the matrix and the formation of a lubricating film on the tribosurface. The coverage of the lubricating film on a worn surface significantly influences the sliding process. However, it is difficult to quantify the film coverage owing to the thin and discontinuous character of the lubricating film and the high roughness of the worn surface. A quantitative characterization of the lubricating film coverage based on X-ray photoelectron spectroscopy (XPS) analysis was developed in this study. The friction tests of Cu-MoS2 composites with a MoS2 content of 0-40 vol% were conducted, and the worn surfaces of the composites were observed and analyzed. Further, the influence of the MoS2 volume content on the coverage of the lubricating film on the worn surface was investigated. The relationships among the volume fraction of the lubricant, coverage of the lubricating film, and the friction coefficient were established. The friction model for the metal matrix self-lubricating composites was developed and verified to facilitate the composition design and friction coefficient prediction of self-lubricating composites.


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Friction of metal-matrix self-lubricating composites: Relationships among lubricant content, lubricating film coverage, and friction coefficient

Show Author's information Jinkun XIAO1,2( )Yuqing WU1Wei ZHANG1Juan CHEN3Chao ZHANG1
College of Mechanical Engineering, Yangzhou University, Yangzhou 225127, China
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Testing Center, Yangzhou University, Yangzhou 225009, China

Abstract

Metal-matrix self-lubricating composites can exhibit excellent tribological properties owing to the release of solid lubricant from the matrix and the formation of a lubricating film on the tribosurface. The coverage of the lubricating film on a worn surface significantly influences the sliding process. However, it is difficult to quantify the film coverage owing to the thin and discontinuous character of the lubricating film and the high roughness of the worn surface. A quantitative characterization of the lubricating film coverage based on X-ray photoelectron spectroscopy (XPS) analysis was developed in this study. The friction tests of Cu-MoS2 composites with a MoS2 content of 0-40 vol% were conducted, and the worn surfaces of the composites were observed and analyzed. Further, the influence of the MoS2 volume content on the coverage of the lubricating film on the worn surface was investigated. The relationships among the volume fraction of the lubricant, coverage of the lubricating film, and the friction coefficient were established. The friction model for the metal matrix self-lubricating composites was developed and verified to facilitate the composition design and friction coefficient prediction of self-lubricating composites.

Keywords: friction coefficient, self-lubricating composites, XPS, lubricating film

References(38)

[1]
Y F Su, Y S Zhang, J J Song, L T Hu. Tribological behavior and lubrication mechanism of self-lubricating ceramic/metal composites: The effect of matrix type on the friction and wear properties. Wear 372-373: 130-138 (2017)
[2]
S M Sharma, A Anand. Solid lubrication in iron based materials-a review. Tribol Ind 38(3): 318-331 (2016)
[3]
J D B De Mello, C Binder, G Hammes, R Binder, A N Klein. Tribological behaviour of sintered iron based self-lubricating composites. Friction 5(3): 285-307 (2017)
[4]
T W Scharf, S V Prasad. Solid lubricants: A review. J Mater Sci 48(2): 511-531 (2013)
[5]
M Chhowalla, G A J Amaratunga. Thin films of fullerene- like MoS2 nanoparticles with ultra-low friction and wear. Nature 407(6801): 164-167 (2000)
[6]
W Wang, G X Xie, J B Luo. Black phosphorus as a new lubricant. Friction 6(1): 116-142 (2018)
[7]
S J Shiao, T Z Wang. Dry self-lubricating composites. Compos: Part B 27(5): 459-465 (1996)
[8]
J K Xiao, L Zhang, K C Zhou, X P Wang. Microscratch behavior of copper-graphite composites. Tribol Int 57: 38-45 (2013)
[9]
S Mahathanabodee, T Palathai, S Raadnui, R Tongsri, N Sombatsompop. Dry sliding wear behavior of SS316L composites containing h-BN and MoS2 solid lubricants. Wear 316(1-2): 37-48 (2014)
[10]
J Kováčik, Š Emmer, J Bielek, L Keleši. Effect of composition on friction coefficient of Cu-graphite composites. Wear 265(3-4): 417-421 (2008)
[11]
F Akhlaghi, A Zare-Bidaki. Influence of graphite content on the dry sliding and oil impregnated sliding wear behavior of Al 2024-graphite composites produced by in situ powder metallurgy method. Wear 266(1-2): 37-45 (2009)
[12]
Y X Wu, F X Wang, Y Q Cheng, N P Chen. A study of the optimization mechanism of solid lubricant concentration in NiMoS2 self-lubricating composite. Wear 205(1-2): 64-70 (1997)
[13]
J K Xiao, W Zhang, L M Liu, L Zhang, C Zhang. Tribological behavior of copper-molybdenum disulfide composites. Wear 384-385: 61-71 (2017)
[14]
P K Rohatgi, Y Liu, M Yin, T L Barr. Tribological behavior and surface analysis of tribodeformed AI alloy-50 pet graphite particle composites. Metall Trans A 22(6): 1435-1441 (1991)
[15]
N Axén, I M Hutchings, S Jacobson. A model for the friction of multiphase materials in abrasion. Tribol Int 29(6): 467-475 (1996)
[16]
P van Trinh, T B Trung, N B Thang, B H Thang, T X Tinh, L D Quang, D D Phuong, P N Minh. Calculation of the friction coefficient of Cu matrix composite reinforced by carbon nanotubes. Comp Mater Sci 49(4 Suppl 1): S239-S241 (2010)
[17]
J P Song, M Valefi, M de Rooij, D J Schipper. A mechanical model for surface layer formation on self-lubricating ceramic composites. Wear 268(9-10): 1072-1079 (2010)
[18]
M Valefi, M de Rooij, M Mokhtari, D J Schipper. Modelling of a thin soft layer on a self-lubricating ceramic composite. Wear 303(1-2): 178-184 (2013)
[19]
Z S Xu, Q X Zhang, X J Huang, R Liu, W Z Zhai, K Yang, Q S Zhu. An approximate model for the migration of solid lubricant on metal matrix self-lubricating composites. Tribol Int 93: 104-114 (2016)
[20]
F P Bowden, D Tabor. The Friction and Lubrication of Solids. Oxford (UK): Clarendon Press, 1964.
[21]
W G Sawyer, P L Dickrell. A fractional coverage model for gas-surface interaction in reciprocating sliding contacts. Wear 256(1-2): 73-80 (2004)
[22]
R Pudjoprawoto, P Dougherty, C F Higgs III. A volumetric fractional coverage model to predict frictional behavior for in situ transfer film lubrication. Wear 304(1-2): 173-182 (2013)
[23]
E Y A Wornyoh, C F Higgs III. An asperity-based fractional coverage model for transfer films on a tribological surface. Wear 270(3-4): 127-139 (2011)
[24]
T A Blanchet, W G Sawyer. Differential application of wear models to fractional thin films. Wear 251(1-12): 1003-1008 (2001)
[25]
J Ye, H S Khare, D L Burris. Quantitative characterization of solid lubricant transfer film quality. Wear 316(1-2): 133-143 (2014)
[26]
D R Haidar, J Ye, A C Moore, D L Burris. Assessing quantitative metrics of transfer film quality as indicators of polymer wear performance. Wear 380-381: 78-85 (2017)
[27]
H Q Cao, Z Y Qian, L Zhang, J K Xiao, K C Zhou. Tribological behavior of Cu matrix composites containing graphite and tungsten disulfide. Tribol Trans 57(6): 1037-1043 (2014)
[28]
L Zhang, J K Xiao, K C Zhou. Sliding wear behavior of silver-molybdenum disulfide composite. Tribol Trans 55(4): 473-480 (2012)
[29]
P K Rohatgi, Y Liu, M Yin, T L Barr. A surface-analytical study of tribodeformed aluminum alloy 319-10 vol.% graphite particle composite. Mater Sci Eng A 123(2): 213-218 (1990)
[30]
D Mandrino, B Podgornik. XPS investigations of tribofilms formed on CrN coatings. Appl Surf Sci 396: 554-559 (2017)
[31]
P J Blau, C S Yust. Microfriction studies of model self- lubricating surfaces. Surf Coat Technol 62(1-3): 380-387 (1993)
[32]
W L Ma, J J Lu. Effect of surface texture on transfer layer formation and tribological behaviour of copper-graphite composite. Wear 270(3-4): 218-229 (2011)
[33]
J E Wilson, F H Stott, G C Wood. The development of wear- protective oxides and their influence on sliding friction. Proc Roy Soc A: Mathem, Phys Eng Sci 369(1739): 557-574 (1980)
[34]
P Ghods, O B Isgor, J R Brown, F Bensebaa, D Kingston. XPS depth profiling study on the passive oxide film of carbon steel in saturated calcium hydroxide solution and the effect of chloride on the film properties. Appl Surf Sci 257(10): 4669-4677 (2011)
[35]
D Chasoglou, E Hryha, M Norell, L Nyborg. Characterization of surface oxides on water-atomized steel powder by XPS/ AES depth profiling and nano-scale lateral surface analysis. Appl Surf Sci 268: 496-506 (2013)
[36]
Y Busby, E J W List-Kratochvil, J J Pireaux. Chemical analysis of the interface in bulk-heterojunction solar cells by X-ray photoelectron spectroscopy depth profiling. ACS Appl Mater Interfaces 9(4): 3842-3848 (2017)
[37]
M A Baker, R Gilmore, C Lenardi, W Gissler. XPS investigation of preferential sputtering of S from MoS2 and determination of MoSx stoichiometry from Mo and S peak positions. Appl Surf Sci 150(1-4): 255-262 (1999)
[38]
R Steinberger, J Walter, T Greunz, J Duchoslav, M Arndt, S Molodtsov, D C Meyer, D Stifter. XPS study of the effects of long-term Ar+ ion and Ar cluster sputtering on the chemical degradation of hydrozincite and iron oxide. Corros Sci 99: 66-75 (2015)
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Publication history

Received: 06 May 2018
Revised: 30 July 2018
Accepted: 29 December 2018
Published: 27 March 2019
Issue date: June 2020

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© The author(s) 2019

Acknowledgements

The authors would like to thank the National Natural Science Foundation of China (Grant No. 51804272), Natural Science Foundation of Jiangsu Province (Grant No. BK20160472), Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 17KJB460017), Project funded by China Postdoctoral Science Foundation (Grant No. 2018M640526), Jiangsu Planned Projects for Postdoctoral Research Funds (Grant No. 1601095C and 2018K073C), Postgraduate Research & Practice Innovation Program of Jiangsu Province (Grant No. SJCX17_0623), Marine Science and Technology Project of Jiangsu Province (Grant No. HY2017-10), Cooperation Funding of Yangzhou City-Yangzhou University (Grant No. YZU201722), and Jiangdu Advanced Equipment Engineering Institute of Yangzhou University (Grant No. 2017-01) for the financial support provided.

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